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Thermal stability, latent heat and flame retardant properties of the thermal energy storage phase change materials based on paraffin/high density polyethylene composites

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  • Cai, Yibing
  • Wei, Qufu
  • Huang, Fenglin
  • Lin, Shiliang
  • Chen, Fang
  • Gao, Weidong

Abstract

In the present work, the thermal energy storage phase change materials (PCM) based on paraffin/high density polyethylene (HDPE) composites were prepared by using twin-screw extruder technique. The morphology and properties of the PCM composites based on the flame retardant system with expanded graphite (EG) and ammonium polyphosphate (APP) were characterized by Scanning electron microscope (SEM), Differential scanning calorimeter (DSC), Thermogravimetric analyses (TGA) and Cone calorimeter tests. It was observed from SEM images that paraffin dispersed well in the three-dimensional net structure formed by the HDPE. The SEM images also indicated that the EG and APP were well dispersed in the PCM composites. The DSC measurements indicated that the additives of flame retardant had little effect on the temperatures of phase change peaks and thermal energy storage property. The TGA results showed that the loadings of the EG and APP increased the temperature of the maximum weight loss and the charred residue of the PCM composites at 650°C, contributing to the improved thermal stability properties. It was revealed from the Cone calorimeter tests that the peak of heat release rate (PHRR) decreased significantly. To further investigate the synergistic effect between the EG and APP, it was observed from SEM images that the homogeneous and compact charred residue structure after combustion contributed to the enhanced thermal stability, improved flammability and increased self-extinguishing properties of the PCM composites.

Suggested Citation

  • Cai, Yibing & Wei, Qufu & Huang, Fenglin & Lin, Shiliang & Chen, Fang & Gao, Weidong, 2009. "Thermal stability, latent heat and flame retardant properties of the thermal energy storage phase change materials based on paraffin/high density polyethylene composites," Renewable Energy, Elsevier, vol. 34(10), pages 2117-2123.
    • Handle: RePEc:eee:renene:v:34:y:2009:i:10:p:2117-2123
    DOI: 10.1016/j.renene.2009.01.017
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    References listed on IDEAS

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    Cited by:

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    3. Sotomayor, M.E. & Krupa, I. & Várez, A. & Levenfeld, B., 2014. "Thermal and mechanical characterization of injection moulded high density polyethylene/paraffin wax blends as phase change materials," Renewable Energy, Elsevier, vol. 68(C), pages 140-145.
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    7. Wang, Yi & Xia, Tian Dong & Feng, Hui Xia & Zhang, Han, 2011. "Stearic acid/polymethylmethacrylate composite as form-stable phase change materials for latent heat thermal energy storage," Renewable Energy, Elsevier, vol. 36(6), pages 1814-1820.
    8. He, Fang & Wang, Xiaodong & Wu, Dezhen, 2014. "New approach for sol–gel synthesis of microencapsulated n-octadecane phase change material with silica wall using sodium silicate precursor," Energy, Elsevier, vol. 67(C), pages 223-233.
    9. Kenisarin, Murat M. & Kenisarina, Kamola M., 2012. "Form-stable phase change materials for thermal energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(4), pages 1999-2040.
    10. Sittisart, Pongphat & Farid, Mohammed M., 2011. "Fire retardants for phase change materials," Applied Energy, Elsevier, vol. 88(9), pages 3140-3145.
    11. Paneliya, Sagar & Khanna, Sakshum & Utsav, & Singh, Ayush Pratap & Patel, Yash Kumar & Vanpariya, Anjali & Makani, Nisha Hiralal & Banerjee, Rupak & Mukhopadhyay, Indrajit, 2021. "Core shell paraffin/silica nanocomposite: A promising phase change material for thermal energy storage," Renewable Energy, Elsevier, vol. 167(C), pages 591-599.
    12. Rathod, Manish K. & Banerjee, Jyotirmay, 2013. "Thermal stability of phase change materials used in latent heat energy storage systems: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 246-258.
    13. Meysam Nazari & Mohamed Jebrane & Nasko Terziev, 2020. "Bio-Based Phase Change Materials Incorporated in Lignocellulose Matrix for Energy Storage in Buildings—A Review," Energies, MDPI, vol. 13(12), pages 1-25, June.
    14. Wang, Xianglei & Guo, Quangui & Wang, Junzhong & Zhong, Yajuan & Wang, Liyong & Wei, Xinghai & Liu, Lang, 2013. "Thermal conductivity enhancement of form-stable phase-change composites by milling of expanded graphite, micro-capsules and polyethylene," Renewable Energy, Elsevier, vol. 60(C), pages 506-509.
    15. Rao, Zhonghao & Wang, Shuangfeng, 2011. "A review of power battery thermal energy management," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(9), pages 4554-4571.
    16. Li, Dan & Wang, Jianping & Wang, Yanan & Li, Wei & Wang, Xuechen & Shi, Haifeng & Zhang, Xingxiang, 2016. "Effect of N-isopropylacrylamide on the preparation and properties of microencapsulated phase change materials," Energy, Elsevier, vol. 106(C), pages 221-230.
    17. Giro-Paloma, Jessica & Martínez, Mònica & Cabeza, Luisa F. & Fernández, A. Inés, 2016. "Types, methods, techniques, and applications for microencapsulated phase change materials (MPCM): A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 1059-1075.
    18. Tatsidjodoung, Parfait & Le Pierrès, Nolwenn & Luo, Lingai, 2013. "A review of potential materials for thermal energy storage in building applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 327-349.

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