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Synergistic effect of acid sites and a gallium-based modified meso-/microporous catalyst for the pyrolysis of biomass

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  • Wei, Xiaocui
  • Cao, Yang
  • Li, Jin

Abstract

Single-metal and bimetal catalysts were synthesized by the modification of a meso-/microporous composite catalyst (ZSM-5@SBA-15) with the oxides of gallium, zinc, and nickel by ion exchange (iex) and impregnation (imp). The catalysts were characterized by XRD, SEM, TEM, XPS, Py-IR, N2-adsorption-desorption and other techniques. The results revealed that the metal is successfully introduced into the catalyst and that the presence of the metal promotes the conversion of the Brönsted acid to the Lewis acid. The catalysts were applied for biomass pyrolysis to produce bio-oil, and the results revealed that the yields of high value-added products of hydrocarbons (e.g., toluene and naphthalene) obtained by catalytic pyrolysis over bimetal catalysts are significantly improved in comparison with those over a non-metal modified catalyst. Moreover, the possible mechanism for catalytic pyrolysis over the best-performing catalyst of Ga/Zn-ZSM-5@SBA-15-iex (gallium, zinc-modified meso-/microporous ZSM-5@SBA-15 by the ion-exchange method) with the highest aromatic selectivity and effective reduction of carbonyl compounds (e.g., carboxides) was proposed by assuming the systematic comparison of structural features and catalytic performances of various metal/ZSM-5@SBA-15-type catalysts. The study provides guidance for the development of multifunctional catalysts with a synergistic effect of acid sites in the presence of a metal.

Suggested Citation

  • Wei, Xiaocui & Cao, Yang & Li, Jin, 2022. "Synergistic effect of acid sites and a gallium-based modified meso-/microporous catalyst for the pyrolysis of biomass," Renewable Energy, Elsevier, vol. 191(C), pages 580-590.
    • Handle: RePEc:eee:renene:v:191:y:2022:i:c:p:580-590
    DOI: 10.1016/j.renene.2022.04.048
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    References listed on IDEAS

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    1. Vichaphund, Supawan & Aht-ong, Duangdao & Sricharoenchaikul, Viboon & Atong, Duangduen, 2015. "Production of aromatic compounds from catalytic fast pyrolysis of Jatropha residues using metal/HZSM-5 prepared by ion-exchange and impregnation methods," Renewable Energy, Elsevier, vol. 79(C), pages 28-37.
    2. Wei, Xiaocui & Xue, Xiangfei & Wu, Liu & Yu, Haozhe & Liang, Jie & Sun, Yifei, 2020. "High-grade bio-oil produced from coconut shell: A comparative study of microwave reactor and core-shell catalyst," Energy, Elsevier, vol. 212(C).
    3. Kostyniuk, Andrii & Bajec, David & Likozar, Blaž, 2022. "Catalytic hydrocracking reactions of tetralin biomass tar model compound to benzene, toluene and xylenes (BTX) over metal-modified ZSM-5 in ambient pressure reactor," Renewable Energy, Elsevier, vol. 188(C), pages 240-255.
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    Cited by:

    1. Yang, Xinyu & Shao, Shanshan & Li, Xiaohua & Tang, Dong, 2023. "Catalytic transfer hydrogenation of bio-oil over biochar-based CuO catalyst using methanol as hydrogen donor," Renewable Energy, Elsevier, vol. 211(C), pages 21-30.
    2. Wei, Xiaocui & Liu, Yanan & Cao, Yang & Li, Jin & Meng, Xianghao & Zhang, Zhao & Jiang, Zhongyi, 2022. "Hierarchical gallium-modified ZSM-5@SBA-15 for the catalytic pyrolysis of biomass into hydrocarbons," Renewable Energy, Elsevier, vol. 200(C), pages 1037-1046.

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