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Transesterification of soybean oil at room temperature using biowaste as catalyst; an experimental investigation on the effect of co-solvent on biodiesel yield

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  • Laskar, Ikbal Bahar
  • Deshmukhya, Tuhin
  • Bhanja, Piyali
  • Paul, Bappi
  • Gupta, Rajat
  • Chatterjee, Sushovan

Abstract

We report herein, Soybean oil was shaped to biodiesel using CaO as heterogeneous catalyst and acetone as cosolvent by employing transesterification reaction at room temperature. In order to prepare active CaO catalyst, waste snail shell was calcined at 800 °C. The prepared catalyst was characterized by XRD, SEM, TEM, EDS, TGA, FTIR, XRF, CO2-TPD, XPS and BET. Biodiesel yield of 98% was achieved with the optimized reaction parameters such as acetone loading of 20 wt% of oil, reaction time of 2 h, catalyst loading of 3 wt% and oil to methanol molar ratio of 1/6. Catalyst can be reused up to 11th cycles. It was concluded from the results that this waste material derived heterogeneous catalyst can replace homogeneous catalyst.

Suggested Citation

  • Laskar, Ikbal Bahar & Deshmukhya, Tuhin & Bhanja, Piyali & Paul, Bappi & Gupta, Rajat & Chatterjee, Sushovan, 2020. "Transesterification of soybean oil at room temperature using biowaste as catalyst; an experimental investigation on the effect of co-solvent on biodiesel yield," Renewable Energy, Elsevier, vol. 162(C), pages 98-111.
    • Handle: RePEc:eee:renene:v:162:y:2020:i:c:p:98-111
    DOI: 10.1016/j.renene.2020.08.011
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    1. Krishnamurthy, K.N. & Sridhara, S.N. & Ananda Kumar, C.S., 2020. "Optimization and kinetic study of biodiesel production from Hydnocarpus wightiana oil and dairy waste scum using snail shell CaO nano catalyst," Renewable Energy, Elsevier, vol. 146(C), pages 280-296.
    2. Taherkhani, M. & Sadrameli, S.M., 2018. "An improvement and optimization study of biodiesel production from linseed via in-situ transesterification using a co-solvent," Renewable Energy, Elsevier, vol. 119(C), pages 787-794.
    3. Pandit, Priti R. & Fulekar, M.H., 2019. "Biodiesel production from microalgal biomass using CaO catalyst synthesized from natural waste material," Renewable Energy, Elsevier, vol. 136(C), pages 837-845.
    4. Farobie, Obie & Sasanami, Kazuma & Matsumura, Yukihiko, 2015. "A novel spiral reactor for biodiesel production in supercritical ethanol," Applied Energy, Elsevier, vol. 147(C), pages 20-29.
    5. Aboelazayem, Omar & Gadalla, Mamdouh & Saha, Basudeb, 2018. "Biodiesel production from waste cooking oil via supercritical methanol: Optimisation and reactor simulation," Renewable Energy, Elsevier, vol. 124(C), pages 144-154.
    6. Goembira, Fadjar & Saka, Shiro, 2015. "Advanced supercritical Methyl acetate method for biodiesel production from Pongamia pinnata oil," Renewable Energy, Elsevier, vol. 83(C), pages 1245-1249.
    7. Goli, Jibril & Sahu, Omprakash, 2018. "Development of heterogeneous alkali catalyst from waste chicken eggshell for biodiesel production," Renewable Energy, Elsevier, vol. 128(PA), pages 142-154.
    8. Abdullah, Sharifah Hanis Yasmin Sayid & Hanapi, Nur Hanis Mohamad & Azid, Azman & Umar, Roslan & Juahir, Hafizan & Khatoon, Helena & Endut, Azizah, 2017. "A review of biomass-derived heterogeneous catalyst for a sustainable biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 1040-1051.
    9. Yaakob, Zahira & Mohammad, Masita & Alherbawi, Mohammad & Alam, Zahangir & Sopian, Kamaruzaman, 2013. "Overview of the production of biodiesel from Waste cooking oil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 184-193.
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    1. Haris Mahmood Khan & Tanveer Iqbal & Saima Yasin & Muhammad Irfan & Muhammad Mujtaba Abbas & Ibham Veza & Manzoore Elahi M. Soudagar & Anas Abdelrahman & Md. Abul Kalam, 2022. "Heterogeneous Catalyzed Biodiesel Production Using Cosolvent: A Mini Review," Sustainability, MDPI, vol. 14(9), pages 1-11, April.
    2. Lau, Pak-Chung & Kwong, Tsz-Lung & Yung, Ka-Fu, 2022. "Manganese glycerolate catalyzed simultaneous esterification and transesterification: The kinetic and mechanistic study, and application in biodiesel and bio-lubricants synthesis," Renewable Energy, Elsevier, vol. 189(C), pages 549-558.
    3. Yusuff, Adeyinka Sikiru & Gbadamosi, Afeez Olayinka & Atray, Neeraj, 2022. "Development of a zeolite supported CaO derived from chicken eggshell as active base catalyst for used cooking oil biodiesel production," Renewable Energy, Elsevier, vol. 197(C), pages 1151-1162.

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