IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v147y2015icp20-29.html
   My bibliography  Save this article

A novel spiral reactor for biodiesel production in supercritical ethanol

Author

Listed:
  • Farobie, Obie
  • Sasanami, Kazuma
  • Matsumura, Yukihiko

Abstract

A spiral reactor is proposed as a novel reactor design for biodiesel production under supercritical conditions. Since the spiral reactor serves as a heat exchanger, it offers the advantage of reduced apparatus space compared to conventional supercritical equipment. Experimental investigations were carried out at reaction temperatures of 270–400°C, pressure of 20MPa, oil-to-ethanol molar ratio of 1:40, and reaction times of 3–30min. An FAEE yield of 0.937mol/mol was obtained in a short reaction time of 30min at 350°C and oil-to-ethanol molar ratio of 1:40 under a reactor pressure of 20MPa. The spiral reactor was not only as effective as conventional reactor in terms of transesterification reactor but also was superior in terms of heat recovery. A second-order kinetic model describing the transesterification of canola oil in supercritical ethanol was proposed, and the reaction was observed to follow Arrhenius behavior. The corresponding reaction rate constants and the activation energies as well as pre-exponential factors were determined.

Suggested Citation

  • Farobie, Obie & Sasanami, Kazuma & Matsumura, Yukihiko, 2015. "A novel spiral reactor for biodiesel production in supercritical ethanol," Applied Energy, Elsevier, vol. 147(C), pages 20-29.
    • Handle: RePEc:eee:appene:v:147:y:2015:i:c:p:20-29
    DOI: 10.1016/j.apenergy.2015.02.033
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S030626191500210X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2015.02.033?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Oliveira, João Felipe G. & Lucena, Izabelly Larissa & Saboya, Rosana M. Alves & Rodrigues, Marcelo L. & Torres, Antonio Eurico B. & Fernandes, Fabiano A. Narciso & Cavalcante, Célio L. & Parente, Expe, 2010. "Biodiesel production from waste coconut oil by esterification with ethanol: The effect of water removal by adsorption," Renewable Energy, Elsevier, vol. 35(11), pages 2581-2584.
    2. Muppaneni, Tapaswy & Reddy, Harvind K. & Patil, Prafulla D. & Dailey, Peter & Aday, Curtis & Deng, Shuguang, 2012. "Ethanolysis of camelina oil under supercritical condition with hexane as a co-solvent," Applied Energy, Elsevier, vol. 94(C), pages 84-88.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Tran, Dang-Thuan & Chang, Jo-Shu & Lee, Duu-Jong, 2017. "Recent insights into continuous-flow biodiesel production via catalytic and non-catalytic transesterification processes," Applied Energy, Elsevier, vol. 185(P1), pages 376-409.
    2. Olalekan Alade & Dhafer Al Shehri & Mohamed Mahmoud & Kyuro Sasaki, 2019. "Viscosity–Temperature–Pressure Relationship of Extra-Heavy Oil (Bitumen): Empirical Modelling versus Artificial Neural Network (ANN)," Energies, MDPI, vol. 12(12), pages 1-13, June.
    3. Andreo-Martínez, Pedro & Ortiz-Martínez, Víctor Manuel & García-Martínez, Nuria & de los Ríos, Antonia Pérez & Hernández-Fernández, Francisco José & Quesada-Medina, Joaquín, 2020. "Production of biodiesel under supercritical conditions: State of the art and bibliometric analysis," Applied Energy, Elsevier, vol. 264(C).
    4. Karmakar, Bisheswar & Pal, Sucharita & Gopikrishna, Konga & Tiwari, Onkar Nath & Halder, Gopinath, 2022. "Injection of superheated C1 and C3 alcohols in non-edible Pongamia pinnata oil for semi-continuous uncatalyzed biodiesel synthesis," Renewable Energy, Elsevier, vol. 185(C), pages 850-861.
    5. Sina Faizollahzadeh Ardabili & Bahman Najafi & Meysam Alizamir & Amir Mosavi & Shahaboddin Shamshirband & Timon Rabczuk, 2018. "Using SVM-RSM and ELM-RSM Approaches for Optimizing the Production Process of Methyl and Ethyl Esters," Energies, MDPI, vol. 11(11), pages 1-19, October.
    6. Laskar, Ikbal Bahar & Deshmukhya, Tuhin & Bhanja, Piyali & Paul, Bappi & Gupta, Rajat & Chatterjee, Sushovan, 2020. "Transesterification of soybean oil at room temperature using biowaste as catalyst; an experimental investigation on the effect of co-solvent on biodiesel yield," Renewable Energy, Elsevier, vol. 162(C), pages 98-111.
    7. Verma, Puneet & Sharma, M.P. & Dwivedi, Gaurav, 2016. "Impact of alcohol on biodiesel production and properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 319-333.
    8. Živković, Snežana B. & Veljković, Milan V. & Banković-Ilić, Ivana B. & Krstić, Ivan M. & Konstantinović, Sandra S. & Ilić, Slavica B. & Avramović, Jelena M. & Stamenković, Olivera S. & Veljković, Vlad, 2017. "Technological, technical, economic, environmental, social, human health risk, toxicological and policy considerations of biodiesel production and use," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 222-247.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Verma, Puneet & Sharma, M.P. & Dwivedi, Gaurav, 2016. "Impact of alcohol on biodiesel production and properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 319-333.
    2. Jazzar, Souhir & Olivares-Carrillo, Pilar & Pérez de los Ríos, Antonia & Marzouki, Mohamed Néjib & Acién-Fernández, Francisco Gabriel & Fernández-Sevilla, José María & Molina-Grima, Emilio & Smaali, I, 2015. "Direct supercritical methanolysis of wet and dry unwashed marine microalgae (Nannochloropsis gaditana) to biodiesel," Applied Energy, Elsevier, vol. 148(C), pages 210-219.
    3. Choi, Oh Kyung & Park, Jo Yong & Kim, Jae-Kon & Lee, Jae Woo, 2019. "Bench-scale production of sewage sludge derived-biodiesel (SSD-BD) and upgrade of its quality," Renewable Energy, Elsevier, vol. 141(C), pages 914-921.
    4. Liu, Chien-Hung & Huang, Chien-Chang & Wang, Yao-Wen & Lee, Duu-Jong & Chang, Jo-Shu, 2012. "Biodiesel production by enzymatic transesterification catalyzed by Burkholderia lipase immobilized on hydrophobic magnetic particles," Applied Energy, Elsevier, vol. 100(C), pages 41-46.
    5. Monteiro, Rodolpho R.C. & Arana-Peña, Sara & da Rocha, Thays N. & Miranda, Letícia P. & Berenguer-Murcia, Ángel & Tardioli, Paulo W. & dos Santos, José C.S. & Fernandez-Lafuente, Roberto, 2021. "Liquid lipase preparations designed for industrial production of biodiesel. Is it really an optimal solution?," Renewable Energy, Elsevier, vol. 164(C), pages 1566-1587.
    6. Pinto, F. & Martins, S. & Gonçalves, M. & Costa, P. & Gulyurtlu, I. & Alves, A. & Mendes, B., 2013. "Hydrogenation of rapeseed oil for production of liquid bio-chemicals," Applied Energy, Elsevier, vol. 102(C), pages 272-282.
    7. Amani, H. & Ahmad, Z. & Hameed, B.H., 2014. "Synthesis of fatty acid methyl esters via the methanolysis of palm oil over Ca3.5xZr0.5yAlxO3 mixed oxide catalyst," Renewable Energy, Elsevier, vol. 66(C), pages 680-685.
    8. Andreo-Martínez, Pedro & Ortiz-Martínez, Víctor Manuel & García-Martínez, Nuria & de los Ríos, Antonia Pérez & Hernández-Fernández, Francisco José & Quesada-Medina, Joaquín, 2020. "Production of biodiesel under supercritical conditions: State of the art and bibliometric analysis," Applied Energy, Elsevier, vol. 264(C).
    9. Maleki, Esmat & Aroua, Mohamed Kheireddine & Sulaiman, Nik Meriam Nik, 2013. "Improved yield of solvent free enzymatic methanolysis of palm and jatropha oils blended with castor oil," Applied Energy, Elsevier, vol. 104(C), pages 905-909.
    10. Avhad, M.R. & Marchetti, J.M., 2015. "A review on recent advancement in catalytic materials for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 696-718.
    11. Li, Qiang & Xu, Jingyang & Du, Wei & Li, Yang & Liu, Dehua, 2013. "Ethanol as the acyl acceptor for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 25(C), pages 742-748.
    12. D'Amato Villardi, Hugo Gomes & Leal, Monique Ferreira & Pellegrini Pessoa, Fernando Luiz & Salgado, Andréa Medeiros, 2019. "Synthesis of methyl esters through residual feedstock using acid and free catalyst – Proposal of new reactor," Renewable Energy, Elsevier, vol. 131(C), pages 1146-1155.
    13. Kanjaikaew, Utaiwan & Tongurai, Chakrit & Chongkhong, Sininart & Prasertsit, Kulchanat, 2018. "Two-step esterification of palm fatty acid distillate in ethyl ester production: Optimization and sensitivity analysis," Renewable Energy, Elsevier, vol. 119(C), pages 336-344.
    14. Liu, Xiaoyan & Zhu, Fenfen & Zhang, Rongyan & Zhao, Luyao & Qi, Juanjuan, 2021. "Recent progress on biodiesel production from municipal sewage sludge," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:147:y:2015:i:c:p:20-29. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.