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A novel α-Fe2O3/AlOOH(γ-Al2O3) nanocatalyst for efficient biodiesel production from waste oil: Kinetic and thermal studies

Author

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  • Mohamed, Mohamed Mokhatr
  • Bayoumy, W.A.
  • El-Faramawy, Hossam
  • El-Dogdog, Wagdy
  • Mohamed, Ashraf A.

Abstract

Different α-Fe2O3 loading (4–12 wt%) doped nanowires AlOOH/γ-Al2O3 catalysts are synthesized using a deposition hydrothermal technique and thoroughly characterized using XRD, SAED-TEM, FTIR, UV–Vis, N2 sorptiometry and XPS measurements. The 12 wt% α-Fe2O3/AlOOH(γ-Al2O3) catalyst presented the highest fatty acid methyl ester (FAME) Yield that comprised of 100% for virgin oil and 94.3% for the waste one, all performed under mild optimized conditions (60 °C, methanol to oil molar ratio = 6:1, 3 wt% catalyst, reaction rate 600 rpm and within 3 h reaction time). It also shows high recyclability without significant loss in activity because of the superior large surface area (323.3 m2/g), high number of acid sites (0.45 mmol g−1), deep pore volume (0.322 ml/g) and to the exposed active site planes (110) and (214) of α-Fe2O3. The kinetic constant (k = 0.016–0.02 min−1) and the activation energy (Ea = 57.4 kJ mol−1) of the reaction together with ΔH ‡ (59.4 kJ mol−1), ΔG ‡ (+95.9 kJ mol−1) and ΔS ‡ (- 0.108 kJ mol−1) values elaborate that the reaction is endothermic, non-spontaneous and obey an associative path. The fuel properties derived from cottonseed oil exhibited high quality biodiesel comparable to the international (ASTM) standards.

Suggested Citation

  • Mohamed, Mohamed Mokhatr & Bayoumy, W.A. & El-Faramawy, Hossam & El-Dogdog, Wagdy & Mohamed, Ashraf A., 2020. "A novel α-Fe2O3/AlOOH(γ-Al2O3) nanocatalyst for efficient biodiesel production from waste oil: Kinetic and thermal studies," Renewable Energy, Elsevier, vol. 160(C), pages 450-464.
    • Handle: RePEc:eee:renene:v:160:y:2020:i:c:p:450-464
    DOI: 10.1016/j.renene.2020.07.006
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    References listed on IDEAS

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    1. Malhotra, Rashi & Ali, Amjad, 2018. "Lithium-doped ceria supported SBA−15 as mesoporous solid reusable and heterogeneous catalyst for biodiesel production via simultaneous esterification and transesterification of waste cottonseed oil," Renewable Energy, Elsevier, vol. 119(C), pages 32-44.
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    2. Ning, Yilin & Niu, Shengli & Wang, Yongzheng & Zhao, Jianli & Lu, Chunmei, 2021. "Sono-modified halloysite nanotube with NaAlO2 as novel heterogeneous catalyst for biodiesel production: Optimization via GA_BP neural network," Renewable Energy, Elsevier, vol. 175(C), pages 391-404.
    3. Aghel, Babak & Gouran, Ashkan & Parandi, Ehsan & Jumeh, Binta Hadi & Nodeh, Hamid Rashidi, 2022. "Production of biodiesel from high acidity waste cooking oil using nano GO@MgO catalyst in a microreactor," Renewable Energy, Elsevier, vol. 200(C), pages 294-302.
    4. Abdelmigeed, Mai O. & Al-Sakkari, Eslam G. & Hefney, Mahmoud S. & Ismail, Fatma M. & Ahmed, Tamer S. & Ismail, Ibrahim M., 2021. "Biodiesel production catalyzed by NaOH/Magnetized ZIF-8: Yield improvement using methanolysis and catalyst reusability enhancement," Renewable Energy, Elsevier, vol. 174(C), pages 253-261.
    5. Li, Ying & Niu, Shengli & Wang, Jun & Zhou, Wenbo & Wang, Yongzheng & Han, Kuihua & Lu, Chunmei, 2022. "Mesoporous SrTiO3 perovskite as a heterogeneous catalyst for biodiesel production: Experimental and DFT studies," Renewable Energy, Elsevier, vol. 184(C), pages 164-175.

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