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Rhodotorula mucilaginosa: A source of heterogeneous catalyst for biodiesel production from yeast single cell oil and waste cooking oil

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  • Gohain, Minakshi
  • Bardhan, Pritam
  • Laskar, Khairujjaman
  • Sarmah, Saswati
  • Mandal, Manabendra
  • Bora, Utpal
  • Chandra Kalita, Mohan
  • Goud, Vaibhav Vasant
  • Deka, Dhanapati

Abstract

Biodiesel obtained from yeast derived single cell oil (SCO) is considered as an alternative to conventional biodiesel derived from plant oils, having the potential to substitute petroleum-derived transport fuels. In this work, we have developed a heterogeneous potassium hydroxide catalyst (K-RAC) supported on Rhodotorula mucilaginosa deoiled cake activated carbon (RAC) to enhance the conversion of R. mucilaginosa isolate R2 derived SCO as well as waste cooking oil (WCO) to biodiesel. The prepared catalyst was characterized by XRD, FTIR, EDX, SEM, BET and TGA. Basicity of the catalyst was determined by CO2-TPD and the hammet indicator test. The maximum fatty acid methyl esters (FAME) conversion of 96.6% and 98.66% for SCO and WCO respectively were obtained at optimized parameters i.e. 9:1 molar ratio (methanol/oil), 3 wt % of K-RAC loading at 60 °C and reaction time of 3 h. 1H NMR and GCMS was used to confirm the formation of biodiesel. The K-RAC was recycled effectively for five consecutive cycles.

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  • Gohain, Minakshi & Bardhan, Pritam & Laskar, Khairujjaman & Sarmah, Saswati & Mandal, Manabendra & Bora, Utpal & Chandra Kalita, Mohan & Goud, Vaibhav Vasant & Deka, Dhanapati, 2020. "Rhodotorula mucilaginosa: A source of heterogeneous catalyst for biodiesel production from yeast single cell oil and waste cooking oil," Renewable Energy, Elsevier, vol. 160(C), pages 220-230.
    • Handle: RePEc:eee:renene:v:160:y:2020:i:c:p:220-230
    DOI: 10.1016/j.renene.2020.06.063
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    1. Saba, Tony & Estephane, Jane & El Khoury, Bilal & El Khoury, Maroulla & Khazma, Mahmoud & El Zakhem, Henri & Aouad, Samer, 2016. "Biodiesel production from refined sunflower vegetable oil over KOH/ZSM5 catalysts," Renewable Energy, Elsevier, vol. 90(C), pages 301-306.
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    1. Leesing, Ratanaporn & Somdee, Theerasak & Siwina, Siraprapha & Ngernyen, Yuvarat & Fiala, Khanittha, 2022. "Production of 2G and 3G biodiesel, yeast oil, and sulfonated carbon catalyst from waste coconut meal: An integrated cascade biorefinery approach," Renewable Energy, Elsevier, vol. 199(C), pages 1093-1104.
    2. Leesing, Ratanaporn & Siwina, Siraprapha & Ngernyen, Yuvarat & Fiala, Khanittha, 2022. "Innovative approach for co-production of single cell oil (SCO), novel carbon-based solid acid catalyst and SCO-based biodiesel from fallen Dipterocarpus alatus leaves," Renewable Energy, Elsevier, vol. 185(C), pages 47-60.
    3. Singh, Himmat & Ali, Amjad, 2023. "Esterification as well as transesterification of waste oil using potassium imbued tungstophosphoric acid supported graphene oxide as heterogeneous catalyst: Optimization and kinetic modeling," Renewable Energy, Elsevier, vol. 207(C), pages 422-435.
    4. Joseph Antony Sundarsingh Tensingh & Vijayalakshmi Shankar, 2022. "Sustainable Production of Biodiesel Using UV Mutagenesis as a Strategy to Enhance the Lipid Productivity in R. mucilaginosa," Sustainability, MDPI, vol. 14(15), pages 1-15, July.

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