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Preparation and characterization of GO/PEG photo-thermal conversion form-stable composite phase change materials

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  • Li, Min
  • Wang, Chengcheng

Abstract

In this paper, graphene oxide (GO) with full band light absorption and photo-thermal conversion property was selected as the photo-thermal conversion material. The GO/PEG composite phase change material (PCM) was prepared by ultrasound-assisted physical blending. The micro-structure, crystallinity and chemical composition of the composite PCMs were characterized by XRD, SEM, and FT-IR analysis techniques, respectively. The thermal storage properties and photo-thermal conversion performance of GO/PEG composite PCMs were tested by DSC and self-assembled photo-thermal conversion test system. The results showed that the inter-layer spacing of GO was enlarged. PEG was distributed between the layers and surfaces of GO through the capillary force of GO and inter-molecular hydrogen bonding. The latent heat of the GO/PEG composite PCMs were more than 80 J/g and the phase transition temperature was 50.5 °C. The composite PCM could absorb visible light (300–800 nm) and store energy through light drive. Photo-thermal conversion efficiency of the GO/PEG reached 0.75, which indicated that the prepared GO/PEG composite PCMs had great application prospect in the field of photo-thermal conversion.

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  • Li, Min & Wang, Chengcheng, 2019. "Preparation and characterization of GO/PEG photo-thermal conversion form-stable composite phase change materials," Renewable Energy, Elsevier, vol. 141(C), pages 1005-1012.
    • Handle: RePEc:eee:renene:v:141:y:2019:i:c:p:1005-1012
    DOI: 10.1016/j.renene.2019.03.141
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    1. Giro-Paloma, Jessica & Martínez, Mònica & Cabeza, Luisa F. & Fernández, A. Inés, 2016. "Types, methods, techniques, and applications for microencapsulated phase change materials (MPCM): A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 1059-1075.
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    3. Wang, Yunming & Tang, Bingtao & Zhang, Shufen, 2014. "Organic, cross-linking, and shape-stabilized solar thermal energy storage materials: A reversible phase transition driven by broadband visible light," Applied Energy, Elsevier, vol. 113(C), pages 59-66.
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