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Mineral phase transformation of biomass ashes – Experimental and thermochemical calculations

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  • Magdziarz, Aneta
  • Gajek, Marcin
  • Nowak-Woźny, Dorota
  • Wilk, Małgorzata

Abstract

The paper is focused on the thermal characterisation of biomass ashes especially of mineral phase transformation. Ash generated during combustion (with high alkali metal concentration) can deposit and consequently cause serious operating problems such as slagging, fouling and corrosion of metal surface limiting heat transfer. Four biomass ashes with different origin were investigated. The chemical composition of the mineral matter of ashes varied between the samples, but CaO, SiO2, K2O, MgO, P2O5 and Al2O3 are the main compounds of the ashes. The thermal behaviour of ashes was studied using TG-DSC and Ash Fusion Temperatures (AFTs) techniques. In order to describe and understand the mineral matter transformation at high temperatures the FactSage Thermodynamics Model was used. FactSage calculations allowed to predict chemical composition in equilibrium, showed amount of liquid slag and solid phases, and gave information about slagging properties of ashes. A corrosion study of the metal surface used for heat transfer biomass ashes was undertaken. The corrosion behaviour of steel X10CrMoVNb9-1 in the present of biomass ash at 650 °C in 1000 h in furnace. The degradation of the metal surface was investigated by observation of surface morphology using the SEM method. The presence of potassium and chlorine in deposits causes the acceleration of oxidation. They break and peel off the surface easily, thus evidently accelerating corrosion.

Suggested Citation

  • Magdziarz, Aneta & Gajek, Marcin & Nowak-Woźny, Dorota & Wilk, Małgorzata, 2018. "Mineral phase transformation of biomass ashes – Experimental and thermochemical calculations," Renewable Energy, Elsevier, vol. 128(PB), pages 446-459.
    • Handle: RePEc:eee:renene:v:128:y:2018:i:pb:p:446-459
    DOI: 10.1016/j.renene.2017.05.057
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    3. Yi Zhang & Guanmin Zhang & Min Wei & Zhenqiang Gao & Maocheng Tian & Fang He, 2019. "Comparisons of Acid and Water Solubilities of Rice Straw Ash Together with Its Major Ash-Forming Elements at Different Ashing Temperatures: An Experimental Study," Sustainability, MDPI, vol. 11(7), pages 1-18, April.
    4. Yao, Xiwen & Zhao, Zhicheng & Li, Jishuo & Zhang, Bohan & Zhou, Haodong & Xu, Kaili, 2020. "Experimental investigation of physicochemical and slagging characteristics of inorganic constituents in ash residues from gasification of different herbaceous biomass," Energy, Elsevier, vol. 198(C).
    5. Mlonka-Mędrala, Agata & Gołombek, Klaudiusz & Buk, Paulina & Cieślik, Ewelina & Nowak, Wojciech, 2019. "The influence of KCl on biomass ash melting behaviour and high-temperature corrosion of low-alloy steel," Energy, Elsevier, vol. 188(C).
    6. Zhang, Heng & Li, Junguo & Yang, Xin & Song, Shuangshuang & Wang, Zhiqing & Huang, Jiejie & Zhang, Yongqi & Fang, Yitian, 2020. "Influence of coal ash on CO2 gasification reactivity of corn stalk char," Renewable Energy, Elsevier, vol. 147(P1), pages 2056-2063.
    7. Zhou, Tianxing & Zhang, Weiwei & Luo, Siyi & Zuo, Zongliang & Ren, Dongdong, 2023. "The effect of ash fusion characteristic on the structure characteristics of carbon and the migration of potassium during rice straw high-temperature gasification process," Energy, Elsevier, vol. 284(C).
    8. Tomasz Hardy & Amit Arora & Halina Pawlak-Kruczek & Wojciech Rafajłowicz & Jerzy Wietrzych & Łukasz Niedźwiecki & Vishwajeet & Krzysztof Mościcki, 2021. "Non-Destructive Diagnostic Methods for Fire-Side Corrosion Risk Assessment of Industrial Scale Boilers, Burning Low Quality Solid Biofuels—A Mini Review," Energies, MDPI, vol. 14(21), pages 1-15, November.
    9. Zhang, Weiwei & Huang, Sheng & Wu, Shiyong & Wu, Youqing & Gao, Jinsheng, 2020. "Ash fusion characteristics and gasification activity during biomasses co-gasification process," Renewable Energy, Elsevier, vol. 147(P1), pages 1584-1594.
    10. Szwaja, Stanisław & Magdziarz, Aneta & Zajemska, Monika & Poskart, Anna, 2019. "A torrefaction of Sida hermaphrodita to improve fuel properties. Advanced analysis of torrefied products," Renewable Energy, Elsevier, vol. 141(C), pages 894-902.
    11. Wilk, Małgorzata & Śliz, Maciej & Lubieniecki, Bogusław, 2021. "Hydrothermal co-carbonization of sewage sludge and fuel additives: Combustion performance of hydrochar," Renewable Energy, Elsevier, vol. 178(C), pages 1046-1056.
    12. Zhou, Haodong & Xu, Kaili & Yao, Xiwen & Li, Jishuo, 2023. "Mineral transformations and molten mechanism during combustion of biomass ash," Renewable Energy, Elsevier, vol. 216(C).

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