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Synthesis of biodiesel from macaw palm oil using mesoporous solid catalyst comprising 12-molybdophosphoric acid and niobia

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  • da Conceição, Leyvison Rafael V.
  • Carneiro, Livia M.
  • Giordani, Domingos S.
  • de Castro, Heizir F.

Abstract

A combined effect of reaction temperature, ethanol-to-oil molar ratio and catalyst concentration on biodiesel production by H3PMo12O40 (HPMo) supported on niobia from macaw palm oil (Acrocomia aculeata) with high free fatty acid content has been studied herein through the response surface methodology. A 23 face centered central composite design was employed in order to conduct the experimental design and results analysis. Optimum conditions were found to be at 210 °C reaction temperature, 90:1 ethanol-to-oil molar ratio and 20.0% catalyst concentration, rendering high-quality biodiesel (99.65% ester content, 4.90 mm2/s viscosity and low monoacylglycerol and diacylglycerol levels). Such high performance can be associated with the catalyst satisfactory features, as characterized by typical analyses such as X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FT-IR), N2 Adsorption-desorption and Surface acidity. Furthermore, the catalyst can be reused with no notable loss of catalytic activity until the second reaction cycle, thus maintaining an ester content higher than 94%.

Suggested Citation

  • da Conceição, Leyvison Rafael V. & Carneiro, Livia M. & Giordani, Domingos S. & de Castro, Heizir F., 2017. "Synthesis of biodiesel from macaw palm oil using mesoporous solid catalyst comprising 12-molybdophosphoric acid and niobia," Renewable Energy, Elsevier, vol. 113(C), pages 119-128.
    • Handle: RePEc:eee:renene:v:113:y:2017:i:c:p:119-128
    DOI: 10.1016/j.renene.2017.05.080
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    1. Badday, Ali Sabri & Abdullah, Ahmad Zuhairi & Lee, Keat-Teong, 2013. "Ultrasound-assisted transesterification of crude Jatropha oil using alumina-supported heteropolyacid catalyst," Applied Energy, Elsevier, vol. 105(C), pages 380-388.
    2. Banković-Ilić, Ivana B. & Stojković, Ivan J. & Stamenković, Olivera S. & Veljkovic, Vlada B. & Hung, Yung-Tse, 2014. "Waste animal fats as feedstocks for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 32(C), pages 238-254.
    3. Badday, Ali Sabri & Abdullah, Ahmad Zuhairi & Lee, Keat-Teong, 2013. "Ultrasound-assisted transesterification of crude Jatropha oil using cesium doped heteropolyacid catalyst: Interactions between process variables," Energy, Elsevier, vol. 60(C), pages 283-291.
    4. Gui, M.M. & Lee, K.T. & Bhatia, S., 2008. "Feasibility of edible oil vs. non-edible oil vs. waste edible oil as biodiesel feedstock," Energy, Elsevier, vol. 33(11), pages 1646-1653.
    5. Al-Jammal, Noor & Al-Hamamre, Zayed & Alnaief, Mohammad, 2016. "Manufacturing of zeolite based catalyst from zeolite tuft for biodiesel production from waste sunflower oil," Renewable Energy, Elsevier, vol. 93(C), pages 449-459.
    6. Avhad, M.R. & Marchetti, J.M., 2015. "A review on recent advancement in catalytic materials for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 696-718.
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    1. de Brito, Vitor Lima & Gonçalves, Matheus Arrais & dos Santos, Hiarla Cristina Lima & da Rocha Filho, Geraldo Narciso & da Conceição, Leyvison Rafael Vieira, 2023. "Biodiesel production from waste frying oil using molybdenum over niobia as heterogeneous acid catalyst: Process optimization and kinetics study," Renewable Energy, Elsevier, vol. 215(C).
    2. Borah, Manash Jyoti & Devi, Anuchaya & Borah, Raju & Deka, Dhanapati, 2019. "Synthesis and application of Co doped ZnO as heterogeneous nanocatalyst for biodiesel production from non-edible oil," Renewable Energy, Elsevier, vol. 133(C), pages 512-519.
    3. da Silva, Paula Maria Melo & Gonçalves, Matheus Arrais & da Luz Corrêa, Ana Paula & da Luz, Patrícia Teresa Souza & Zamian, José Roberto & da Rocha Filho, Geraldo Narciso & da Conceição, Leyvison Rafa, 2023. "Preparation and characterization of a novel efficient catalyst based on molybdenum oxide supported over graphene oxide for biodiesel synthesis," Renewable Energy, Elsevier, vol. 211(C), pages 126-139.
    4. Jéssica Siqueira Mancilha Nogueira & João Paulo Alves Silva & Solange I. Mussatto & Livia Melo Carneiro, 2020. "Synthesis and Application of Heterogeneous Catalysts Based on Heteropolyacids for 5-Hydroxymethylfurfural Production from Glucose," Energies, MDPI, vol. 13(3), pages 1-17, February.
    5. Savienne M. F. E. Zorn & Ana Paula T. da Silva & Eduardo H. Bredda & Heitor B. S. Bento & Guilherme A. Pedro & Ana Karine F. Carvalho & Messias Borges Silva & Patrícia C. M. Da Rós, 2022. "In Situ Transesterification of Microbial Biomass for Biolubricant Production Catalyzed by Heteropolyacid Supported on Niobium," Energies, MDPI, vol. 15(4), pages 1-12, February.

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