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Effect of potassium on thermogravimetric behavior and co-pyrolytic kinetics of wood biomass and low density polyethylene

Author

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  • Zhou, Limin
  • Zou, Hongbin
  • Wang, Yun
  • Le, Zhanggao
  • Liu, Zhirong
  • Adesina, Adesoji A.

Abstract

The effect of potassium on the thermogravimetric behavior and co-pyrolytic kinetics of wood sawdust (WS) and low density polyethylene (LDPE) was investigated using a thermogravimetric analyzer. It was found that the co-pyrolysis behavior of the potassium-treated WS/LDPE mixtures were different from the combination of WS and LDPE, and the maximum weight loss between the experimental and calculated values (ΔW) was up to −24.2%. Potassium has a great influence on the pyrolysis of WS/LDPE mixtures, leading to the decrease of the characteristic decomposition temperature (TP1) and the increase of char yield with increasing potassium content. The simulation of possible structures indicates that [K-cellobiose]+ complexes have different configurations and potassium may facilitate the cracking of the glycosidic linkage and the ring-opening reaction. The kinetic analysis indicated that the co-pyrolysis of the potassium-treated WS/LDPE mixtures could be described by three independent first-order reactions. The increase of the potassium contents in the WS/LDPE mixtures causes an increase trend for E and A values in the first decomposition stage but leads to a decreasing trend in the second stage. Furthermore, the kinetic compensation effect (KCE) has been observed in each decomposition stage for the co-pyrolysis of potassium-treated WS/LDPE mixtures.

Suggested Citation

  • Zhou, Limin & Zou, Hongbin & Wang, Yun & Le, Zhanggao & Liu, Zhirong & Adesina, Adesoji A., 2017. "Effect of potassium on thermogravimetric behavior and co-pyrolytic kinetics of wood biomass and low density polyethylene," Renewable Energy, Elsevier, vol. 102(PA), pages 134-141.
  • Handle: RePEc:eee:renene:v:102:y:2017:i:pa:p:134-141
    DOI: 10.1016/j.renene.2016.10.028
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    References listed on IDEAS

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    1. Chen, Wei-Hsin & Kuo, Po-Chih, 2011. "Isothermal torrefaction kinetics of hemicellulose, cellulose, lignin and xylan using thermogravimetric analysis," Energy, Elsevier, vol. 36(11), pages 6451-6460.
    2. Haykiri-Acma, H. & Yaman, S., 2010. "Interaction between biomass and different rank coals during co-pyrolysis," Renewable Energy, Elsevier, vol. 35(1), pages 288-292.
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    2. Mei Yin Ong & Nor-Insyirah Syahira Abdul Latif & Hui Yi Leong & Bello Salman & Pau Loke Show & Saifuddin Nomanbhay, 2019. "Characterization and Analysis of Malaysian Macroalgae Biomass as Potential Feedstock for Bio-Oil Production," Energies, MDPI, vol. 12(18), pages 1-14, September.
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    5. Dhyani, Vaibhav & Bhaskar, Thallada, 2018. "A comprehensive review on the pyrolysis of lignocellulosic biomass," Renewable Energy, Elsevier, vol. 129(PB), pages 695-716.

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