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Microencapsulation of n-dodecane into zirconia shell doped with rare earth: Design and synthesis of bifunctional microcapsules for photoluminescence enhancement and thermal energy storage

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  • Zhang, Ying
  • Wang, Xiaodong
  • Wu, Dezhen

Abstract

We have designed a new type of bifunctional microcapsules composed of an n-dodecane PCM (phase change material) core and a rare-earth-doped zirconia shell for photoluminescence enhancement and thermal energy storage and have synthesized a series of microcapsule samples through in-situ polycondensation in a non-aqueous emulsion templating system. The scanning electron microscopic investigation indicated that the resultant microcapsules presented the regular spheres with a smooth surface and a uniform size distribution, while the transmission electron microscopy showed a well-defined core–shell structure for these microcapsules. The Fourier–transform infrared spectroscopy characterized the chemical compositions of the resultant microcapsules, and the rare-earth elements doped within the zirconia shell were confirmed by energy-dispersive X-ray patterns and X–ray photoelectron spectroscopy. The resultant microcapsules exhibited a good thermal regulation capability with high encapsulation and energy-storage efficiencies. Most of all, the photoluminescence characterization indicated that these rare-earth-doped microcapsules achieved a significant enhancement in emission intensity of the cyan-colored up-conversion and purple-colored down-conversion fluorescence after excited by radiation at wavelengths of 850 and 280 nm, respectively. The enhancement level of emission intensity varied with different rare-earth species and was determined by the bond length of rare-earth ion to oxygen in the solid solution of zirconia host.

Suggested Citation

  • Zhang, Ying & Wang, Xiaodong & Wu, Dezhen, 2016. "Microencapsulation of n-dodecane into zirconia shell doped with rare earth: Design and synthesis of bifunctional microcapsules for photoluminescence enhancement and thermal energy storage," Energy, Elsevier, vol. 97(C), pages 113-126.
    • Handle: RePEc:eee:energy:v:97:y:2016:i:c:p:113-126
    DOI: 10.1016/j.energy.2015.12.114
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    5. Zhang, Xiaoyu & Wang, Xiaodong & Wu, Dezhen, 2016. "Design and synthesis of multifunctional microencapsulated phase change materials with silver/silica double-layered shell for thermal energy storage, electrical conduction and antimicrobial effectivene," Energy, Elsevier, vol. 111(C), pages 498-512.
    6. Sun, Kun & Liu, Huan & Wang, Xiaodong & Wu, Dezhen, 2019. "Innovative design of superhydrophobic thermal energy-storage materials by microencapsulation of n-docosane with nanostructured ZnO/SiO2 shell," Applied Energy, Elsevier, vol. 237(C), pages 549-565.

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