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A two-dimensional distributed activation energy model for pyrolysis of solid fuels

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  • Ma, Junfang
  • Liu, Jiaxun
  • Jiang, Xiumin
  • Zhang, Hai

Abstract

Pyrolysis kinetic models are pivotal for understanding and optimizing the gasification, distillation, and combustion processes. This paper proposes a novel two-dimensional distributed activation energy model (2D-DAEM), which is achieved via extending the classical DAEM to the 2D plane of activation energy E and pre-exponential factor A. The performance of the proposed model was evaluated based upon comprehensive analyses of complex reactions such as co-pyrolysis. The results show that the 2D-DAEM outperforms the classical DAEM in terms of efficiency and accuracy. Specifically, the co-pyrolysis analysis of pine woodchips (PINE) and polyethylene terephthalate (PET), shows that the classical DAEM tends to underestimate the lnA values (i.e., 43.0 for PINE pyrolysis; 42.0 for PET pyrolysis; but 39.2 for PINE&PET co-pyrolysis), while the lnA value of 2D-DAEM (about 43.0 for all) is more reasonable. Additionally, the 2D-DAEM is employed to study the influence of coal particle size on pyrolysis. It is observed that the 25 μm coal has the highest reaction rate under both 500 K and 1500 K iso-thermal processes. As a more normative, reasonable, and accurate model, the proposed 2D-DAEM is bound to enhance the practice of reaction prediction, material analysis, and process design.

Suggested Citation

  • Ma, Junfang & Liu, Jiaxun & Jiang, Xiumin & Zhang, Hai, 2021. "A two-dimensional distributed activation energy model for pyrolysis of solid fuels," Energy, Elsevier, vol. 230(C).
    • Handle: RePEc:eee:energy:v:230:y:2021:i:c:s0360544221011087
    DOI: 10.1016/j.energy.2021.120860
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    1. Brillard, A. & Brilhac, J.F., 2020. "Improvements of global models for the determination of the kinetic parameters associated to the thermal degradation of lignocellulosic materials under low heating rates," Renewable Energy, Elsevier, vol. 146(C), pages 1498-1509.
    2. Navarro, M.V. & López, J.M. & Veses, A. & Callén, M.S. & García, T., 2018. "Kinetic study for the co-pyrolysis of lignocellulosic biomass and plastics using the distributed activation energy model," Energy, Elsevier, vol. 165(PA), pages 731-742.
    3. Fang, Shiwen & Lin, Yousheng & Lin, Yan & Chen, Shu & Shen, Xiangyang & Zhong, Tianming & Ding, Lixing & Ma, Xiaoqian, 2020. "Influence of ultrasonic pretreatment on the co-pyrolysis characteristics and kinetic parameters of municipal solid waste and paper mill sludge," Energy, Elsevier, vol. 190(C).
    4. Xiao, Ruirui & Yang, Wei & Cong, Xingshun & Dong, Kai & Xu, Jie & Wang, Dengfeng & Yang, Xin, 2020. "Thermogravimetric analysis and reaction kinetics of lignocellulosic biomass pyrolysis," Energy, Elsevier, vol. 201(C).
    5. Zadravec, Tomas & Yin, Chungen & Kokalj, Filip & Samec, Niko & Rajh, Boštjan, 2020. "The impacts of different profiles of the grate inlet conditions on freeboard CFD in a waste wood-fired grate boiler," Applied Energy, Elsevier, vol. 268(C).
    6. Duan, Wenjun & Yu, Qingbo & Xie, Huaqing & Qin, Qin, 2017. "Pyrolysis of coal by solid heat carrier-experimental study and kinetic modeling," Energy, Elsevier, vol. 135(C), pages 317-326.
    7. Wu, Junnan & Liao, Yanfen & Lin, Yan & Tian, Yunlong & Ma, Xiaoqian, 2019. "Study on thermal decomposition kinetics model of sewage sludge and wheat based on multi distributed activation energy," Energy, Elsevier, vol. 185(C), pages 795-803.
    8. Li, Mi & Jiang, Lin & He, Jia-Jia & Sun, Jin-Hua, 2019. "Kinetic triplet determination and modified mechanism function construction for thermo-oxidative degradation of waste polyurethane foam using conventional methods and distributed activation energy mode," Energy, Elsevier, vol. 175(C), pages 1-13.
    9. Zhang, Zhiping & Tahir, Nadeem & Li, Yameng & Zhang, Tian & Zhu, Shengnan & Zhang, Quanguo, 2019. "Tailoring of structural and optical parameters of corncobs through ball milling pretreatment," Renewable Energy, Elsevier, vol. 141(C), pages 298-304.
    10. Cai, Junmeng & Wu, Weixuan & Liu, Ronghou, 2014. "An overview of distributed activation energy model and its application in the pyrolysis of lignocellulosic biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 36(C), pages 236-246.
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