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Development and techno-economic study of methanol production from coke-oven gas blended with Linz Donawitz gas

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  • Shin, Sunkyu
  • Lee, Jeong-Keun
  • Lee, In-Beum

Abstract

Coke-oven gas and Linz Donawitz gas are pollutive by-product gases generated from steel plants. The gases are currently combusted or released to atmosphere, but those can be economically utilized as chemical product. Thus, this study proposes improved methanol production process from the gases, by considering two different strategies: efficiency (Case 1) and productivity (Case 2). Both processes are rigorously integrated using Aspen Plus V10 and evaluated from the perspectives of productivity, thermodynamic efficiency, environmental impact, and techno-economics. Compared to Case 1, Case 2 had 2.1 times the productivity but required 3 times natural gas. As a result, Case 1 showed better efficiencies of 58–68% (46–56% in Case 2), reduced larger carbon emission of 425 kmol/h (123 kmol/h in Case 2), and had lower minimum selling price of 371 $/tonne (398 $/tonne in Case 2). Two proposed processes are also economically superior than similar previous processes (550–712 $/tonne). This study confirms that both presented novel processes are sustainable and economically viable, and also improves the understanding of methanol production from the waste gases of steel production.

Suggested Citation

  • Shin, Sunkyu & Lee, Jeong-Keun & Lee, In-Beum, 2020. "Development and techno-economic study of methanol production from coke-oven gas blended with Linz Donawitz gas," Energy, Elsevier, vol. 200(C).
    • Handle: RePEc:eee:energy:v:200:y:2020:i:c:s0360544220306137
    DOI: 10.1016/j.energy.2020.117506
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    References listed on IDEAS

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    9. Yi, Qun & Gong, Min-Hui & Huang, Yi & Feng, Jie & Hao, Yan-Hong & Zhang, Ji-Long & Li, Wen-Ying, 2016. "Process development of coke oven gas to methanol integrated with CO2 recycle for satisfactory techno-economic performance," Energy, Elsevier, vol. 112(C), pages 618-628.
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    8. Bampaou, M. & Haag, S. & Kyriakides, A.-S. & Panopoulos, K.D. & Seferlis, P., 2023. "Optimizing methanol synthesis combining steelworks off-gases and renewable hydrogen," Renewable and Sustainable Energy Reviews, Elsevier, vol. 171(C).
    9. Lopes, J.V.M. & Bresciani, A.E. & Carvalho, K.M. & Kulay, L.A. & Alves, R.M.B., 2021. "Multi-criteria decision approach to select carbon dioxide and hydrogen sources as potential raw materials for the production of chemicals," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).

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