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Optimizing methanol synthesis combining steelworks off-gases and renewable hydrogen

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  • Bampaou, M.
  • Haag, S.
  • Kyriakides, A.-S.
  • Panopoulos, K.D.
  • Seferlis, P.

Abstract

Renewable hydrogen improves the carbon balance of the methanol synthesis process but raises the production costs rendering a suitable hydrogen utilization strategy necessary. This work proposes different operating maps and reactor configurations that lead to improved hydrogen utilization and thus lower production costs. A mixture of steelworks off-gases is investigated as feedstock for the synthesis. At first, the conventional single-reactor loop operation is investigated, whereas in the second part, multi-reactor configurations are proposed to improve the process performance. Crucial operating variables are optimized to achieve optimum hydrogen utilization conditions for the investigated reactor setups. Results showed that recycling improved the performance in the single-reactor but no substantial improvements are observed for the multi-reactor setups. Overall, the four-reactor concept improves significantly the process efficiency that consequently could reduce the associated production costs: 13% lower hydrogen, 30% lower feedstock, 27% lower compression requirements and higher CO2 conversion (63%) per produced methanol unit.

Suggested Citation

  • Bampaou, M. & Haag, S. & Kyriakides, A.-S. & Panopoulos, K.D. & Seferlis, P., 2023. "Optimizing methanol synthesis combining steelworks off-gases and renewable hydrogen," Renewable and Sustainable Energy Reviews, Elsevier, vol. 171(C).
    • Handle: RePEc:eee:rensus:v:171:y:2023:i:c:s1364032122009169
    DOI: 10.1016/j.rser.2022.113035
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    References listed on IDEAS

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    1. Shin, Sunkyu & Lee, Jeong-Keun & Lee, In-Beum, 2020. "Development and techno-economic study of methanol production from coke-oven gas blended with Linz Donawitz gas," Energy, Elsevier, vol. 200(C).
    2. Lundgren, J. & Ekbom, T. & Hulteberg, C. & Larsson, M. & Grip, C.-E. & Nilsson, L. & Tunå, P., 2013. "Methanol production from steel-work off-gases and biomass based synthesis gas," Applied Energy, Elsevier, vol. 112(C), pages 431-439.
    3. Michael Bampaou & Kyriakos Panopoulos & Panos Seferlis & Amaia Sasiain & Stephane Haag & Philipp Wolf-Zoellner & Markus Lehner & Leokadia Rog & Przemyslaw Rompalski & Sebastian Kolb & Nina Kieberger &, 2022. "Economic Evaluation of Renewable Hydrogen Integration into Steelworks for the Production of Methanol and Methane," Energies, MDPI, vol. 15(13), pages 1-26, June.
    4. Yi, Qun & Gong, Min-Hui & Huang, Yi & Feng, Jie & Hao, Yan-Hong & Zhang, Ji-Long & Li, Wen-Ying, 2016. "Process development of coke oven gas to methanol integrated with CO2 recycle for satisfactory techno-economic performance," Energy, Elsevier, vol. 112(C), pages 618-628.
    5. Michael Bampaou & Kyriakos Panopoulos & Panos Seferlis & Spyridon Voutetakis & Ismael Matino & Alice Petrucciani & Antonella Zaccara & Valentina Colla & Stefano Dettori & Teresa Annunziata Branca & Vi, 2021. "Integration of Renewable Hydrogen Production in Steelworks Off-Gases for the Synthesis of Methanol and Methane," Energies, MDPI, vol. 14(10), pages 1-24, May.
    6. Kim, Dongin & Han, Jeehoon, 2020. "Techno-economic and climate impact analysis of carbon utilization process for methanol production from blast furnace gas over Cu/ZnO/Al2O3 catalyst," Energy, Elsevier, vol. 198(C).
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    Cited by:

    1. Alexandros Kafetzis & Michael Bampaou & Giorgos Kardaras & Kyriakos Panopoulos, 2023. "Decarbonization of Former Lignite Regions with Renewable Hydrogen: The Western Macedonia Case," Energies, MDPI, vol. 16(20), pages 1-21, October.
    2. David D. J. Antia, 2023. "Conversion of Waste Synthesis Gas to Desalination Catalyst at Ambient Temperatures," Waste, MDPI, vol. 1(2), pages 1-29, May.

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