IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v188y2019ics0360544219317153.html
   My bibliography  Save this article

Thermodynamic analysis based on simultaneous chemical and phase equilibrium for dehydration of glycerol with methanol

Author

Listed:
  • Jia, Guangxin
  • He, Beibei
  • Ma, Wenlin
  • Sun, Yifan

Abstract

Glycerol can be dehydrated with methanol to produce tri-methyl glyceryl ethers (TMGE) and di-methyl glyceryl ethers (DMGE) as excellent diesel additives. Based on the simultaneous chemical and phase equilibrium, the thermodynamic equilibrium for dehydration of glycerol with methanol was studied in a wide range of reaction conditions (T = 40–300 °C, P = 0.5–7.5 atm and methanol/glycerol = 4:1–8:1 mol/mole). The improved genetic algorithm was applied to minimize Gibbs free energy of system corrected by UNIFAC model, which will provide an alternative of thermodynamic equilibrium analysis for the similar systems containing multi-phases, multi-components and multi-reactions. It was found that glycerol conversion is about 99.9% in the whole study range. The TMGE selectivity decreases with temperature due that the reaction is exothermic, but increases after the temperature rises to a certain value due to endothermic effect of components evaporation. In addition, the effects of pressure and the mole ratio of glycerol to methanol were investigated in this paper. Increasing the feed ratio of methanol to glycerol leads to the TMGE selectivity of 99.7%. More water ranging from 56% to 33% of equilibrium content, is generated with the mole ratio of methanol/glycerol from 4:1 to 8:1. Phase distribution of the equilibrium composition was demonstrated in this paper.

Suggested Citation

  • Jia, Guangxin & He, Beibei & Ma, Wenlin & Sun, Yifan, 2019. "Thermodynamic analysis based on simultaneous chemical and phase equilibrium for dehydration of glycerol with methanol," Energy, Elsevier, vol. 188(C).
    • Handle: RePEc:eee:energy:v:188:y:2019:i:c:s0360544219317153
    DOI: 10.1016/j.energy.2019.116021
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544219317153
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2019.116021?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Monteiro, Marcos Roberto & Kugelmeier, Cristie Luis & Pinheiro, Rafael Sanaiotte & Batalha, Mario Otávio & da Silva César, Aldara, 2018. "Glycerol from biodiesel production: Technological paths for sustainability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 88(C), pages 109-122.
    2. Anuar, Mohd Razealy & Abdullah, Ahmad Zuhairi, 2016. "Challenges in biodiesel industry with regards to feedstock, environmental, social and sustainability issues: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 208-223.
    3. Basha, Syed Ameer & Gopal, K. Raja & Jebaraj, S., 2009. "A review on biodiesel production, combustion, emissions and performance," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(6-7), pages 1628-1634, August.
    4. Beatrice, Carlo & Di Blasio, Gabriele & Guido, Chiara & Cannilla, Catia & Bonura, Giuseppe & Frusteri, Francesco, 2014. "Mixture of glycerol ethers as diesel bio-derivable oxy-fuel: Impact on combustion and emissions of an automotive engine combustion system," Applied Energy, Elsevier, vol. 132(C), pages 236-247.
    5. Atabani, A.E. & Silitonga, A.S. & Badruddin, Irfan Anjum & Mahlia, T.M.I. & Masjuki, H.H. & Mekhilef, S., 2012. "A comprehensive review on biodiesel as an alternative energy resource and its characteristics," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(4), pages 2070-2093.
    6. Chein, Rei-Yu & Yu, Ching-Tsung, 2017. "Thermodynamic equilibrium analysis of water-gas shift reaction using syngases-effect of CO2 and H2S contents," Energy, Elsevier, vol. 141(C), pages 1004-1018.
    7. Gholami, Zahra & Abdullah, Ahmad Zuhairi & Lee, Keat-Teong, 2014. "Dealing with the surplus of glycerol production from biodiesel industry through catalytic upgrading to polyglycerols and other value-added products," Renewable and Sustainable Energy Reviews, Elsevier, vol. 39(C), pages 327-341.
    8. Shahid, Ejaz M. & Jamal, Younis, 2011. "Production of biodiesel: A technical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(9), pages 4732-4745.
    9. Singhabhandhu, Ampaitepin & Tezuka, Tetsuo, 2010. "A perspective on incorporation of glycerin purification process in biodiesel plants using waste cooking oil as feedstock," Energy, Elsevier, vol. 35(6), pages 2493-2504.
    10. Leoneti, Alexandre Bevilacqua & Aragão-Leoneti, Valquiria & de Oliveira, Sonia Valle Walter Borges, 2012. "Glycerol as a by-product of biodiesel production in Brazil: Alternatives for the use of unrefined glycerol," Renewable Energy, Elsevier, vol. 45(C), pages 138-145.
    11. Mohd Noor, C.W. & Noor, M.M. & Mamat, R., 2018. "Biodiesel as alternative fuel for marine diesel engine applications: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 94(C), pages 127-142.
    12. Izquierdo, J.F. & Montiel, M. & Palés, I. & Outón, P.R. & Galán, M. & Jutglar, L. & Villarrubia, M. & Izquierdo, M. & Hermo, M.P. & Ariza, X., 2012. "Fuel additives from glycerol etherification with light olefins: State of the art," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(9), pages 6717-6724.
    13. Ateka, Ainara & Pérez-Uriarte, Paula & Gamero, Mónica & Ereña, Javier & Aguayo, Andrés T. & Bilbao, Javier, 2017. "A comparative thermodynamic study on the CO2 conversion in the synthesis of methanol and of DME," Energy, Elsevier, vol. 120(C), pages 796-804.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhang, Bo & Guo, Yaning & Li, Nian & He, Peng & Guo, Xiangji, 2023. "Experimental study of gas–liquid behavior in three-flow vortex tube with sintered metal porous material as the drain part," Energy, Elsevier, vol. 263(PA).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mohsin Raza & Abrar Inayat & Basim Abu-Jdayil, 2021. "Crude Glycerol as a Potential Feedstock for Future Energy via Thermochemical Conversion Processes: A Review," Sustainability, MDPI, vol. 13(22), pages 1-27, November.
    2. Monteiro, Marcos Roberto & Kugelmeier, Cristie Luis & Pinheiro, Rafael Sanaiotte & Batalha, Mario Otávio & da Silva César, Aldara, 2018. "Glycerol from biodiesel production: Technological paths for sustainability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 88(C), pages 109-122.
    3. Azad, A.K. & Rasul, M.G. & Khan, M.M.K. & Sharma, Subhash C. & Mofijur, M. & Bhuiya, M.M.K., 2016. "Prospects, feedstocks and challenges of biodiesel production from beauty leaf oil and castor oil: A nonedible oil sources in Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 302-318.
    4. Sedghi, Reza & Shahbeik, Hossein & Rastegari, Hajar & Rafiee, Shahin & Peng, Wanxi & Nizami, Abdul-Sattar & Gupta, Vijai Kumar & Chen, Wei-Hsin & Lam, Su Shiung & Pan, Junting & Tabatabaei, Meisam & A, 2022. "Turning biodiesel glycerol into oxygenated fuel additives and their effects on the behavior of internal combustion engines: A comprehensive systematic review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    5. Chakraborty, Rajat & Gupta, Abhishek.K. & Chowdhury, Ratul, 2014. "Conversion of slaughterhouse and poultry farm animal fats and wastes to biodiesel: Parametric sensitivity and fuel quality assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 120-134.
    6. Singh, Paramvir & Varun, & Chauhan, S.R., 2016. "Carbonyl and aromatic hydrocarbon emissions from diesel engine exhaust using different feedstock: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 63(C), pages 269-291.
    7. Savvas L. Douvartzides & Nikolaos D. Charisiou & Kyriakos N. Papageridis & Maria A. Goula, 2019. "Green Diesel: Biomass Feedstocks, Production Technologies, Catalytic Research, Fuel Properties and Performance in Compression Ignition Internal Combustion Engines," Energies, MDPI, vol. 12(5), pages 1-41, February.
    8. Okoye, P.U. & Hameed, B.H., 2016. "Review on recent progress in catalytic carboxylation and acetylation of glycerol as a byproduct of biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 558-574.
    9. Kugelmeier, Cristie Luis & Monteiro, Marcos Roberto & da Silva, Rodrigo & Kuri, Sebastião Elias & Sordi, Vitor Luiz & Della Rovere, Carlos Alberto, 2021. "Corrosion behavior of carbon steel, stainless steel, aluminum and copper upon exposure to biodiesel blended with petrodiesel," Energy, Elsevier, vol. 226(C).
    10. Bhuiya, M.M.K. & Rasul, M.G. & Khan, M.M.K. & Ashwath, N. & Azad, A.K., 2016. "Prospects of 2nd generation biodiesel as a sustainable fuel—Part: 1 selection of feedstocks, oil extraction techniques and conversion technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 1109-1128.
    11. Silva, Wellington Costa & Castro, Maria Priscila Pessanha & Perez, Victor Haber & Machado, Francisco A. & Mota, Leonardo & Sthel, Marcelo Silva, 2016. "Thermal degradation of ethanolic biodiesel: Physicochemical and thermal properties evaluation," Energy, Elsevier, vol. 114(C), pages 1093-1099.
    12. Mofijur, M. & Masjuki, H.H. & Kalam, M.A. & Ashrafur Rahman, S.M. & Mahmudul, H.M., 2015. "Energy scenario and biofuel policies and targets in ASEAN countries," Renewable and Sustainable Energy Reviews, Elsevier, vol. 46(C), pages 51-61.
    13. How, H.G. & Teoh, Y.H. & Krishnan, B. Navaneetha & Le, T.D. & Nguyen, H.T. & Prabhu, C., 2021. "Prediction of optimum Palm Oil Methyl Ester fuel blend for compression ignition engine using Response Surface Methodology," Energy, Elsevier, vol. 234(C).
    14. Mariem Harabi & Soumaya Neji Bouguerra & Fatma Marrakchi & Loukia P. Chrysikou & Stella Bezergianni & Mohamed Bouaziz, 2019. "Biodiesel and Crude Glycerol from Waste Frying Oil: Production, Characterization and Evaluation of Biodiesel Oxidative Stability with Diesel Blends," Sustainability, MDPI, vol. 11(7), pages 1-15, April.
    15. Patel, Alok & Arora, Neha & Mehtani, Juhi & Pruthi, Vikas & Pruthi, Parul A., 2017. "Assessment of fuel properties on the basis of fatty acid profiles of oleaginous yeast for potential biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 604-616.
    16. Agarwal, Swati & Kumari, Sonu & Mudgal, Anurag & Khan, Suphiya, 2020. "Green synthesized nanoadditives in jojoba biodiesel-diesel blends: An improvement of engine performance and emission," Renewable Energy, Elsevier, vol. 147(P1), pages 1836-1844.
    17. Rafael Estevez & Laura Aguado-Deblas & Diego Luna & Felipa M. Bautista, 2019. "An Overview of the Production of Oxygenated Fuel Additives by Glycerol Etherification, Either with Isobutene or tert -Butyl Alcohol, over Heterogeneous Catalysts," Energies, MDPI, vol. 12(12), pages 1-20, June.
    18. Alexandre Bevilacqua Leoneti & Valquiria Aragão-Leoneti & Simone Vasconcelos Ribeiro Galina & Geciane Silveira Porto, 2017. "The methylic versus the ethylic route: considerations about the sustainability of Brazilian biodiesel production," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 19(2), pages 637-651, April.
    19. Nitièma-Yefanova, Svitlana & Coniglio, Lucie & Schneider, Raphaël & Nébié, Roger H.C. & Bonzi-Coulibaly, Yvonne L., 2016. "Ethyl biodiesel production from non-edible oils of Balanites aegyptiaca, Azadirachta indica, and Jatropha curcas seeds – Laboratory scale development," Renewable Energy, Elsevier, vol. 96(PA), pages 881-890.
    20. Sanjid, A. & Masjuki, H.H. & Kalam, M.A. & Rahman, S.M. Ashrafur & Abedin, M.J. & Palash, S.M., 2013. "Impact of palm, mustard, waste cooking oil and Calophyllum inophyllum biofuels on performance and emission of CI engine," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 664-682.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:188:y:2019:i:c:s0360544219317153. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.