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Effects of the extraction solvents in hydrothermal liquefaction processes: Biocrude oil quality and energy conversion efficiency

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  • Watson, Jamison
  • Lu, Jianwen
  • de Souza, Raquel
  • Si, Buchun
  • Zhang, Yuanhui
  • Liu, Zhidan

Abstract

One prevailing issue for assessing the performance of hydrothermal liquefaction is understanding the role of the extraction solvent used for product separation. This study evaluated the extraction agent's impact on the hydrothermal liquefaction products and energy efficiency. Three representative solvents (acetone, dichloromethane, and toluene) were chosen with three representative high-carbohydrate, protein, and ash content feedstocks (Chlorella sp., Nannochloropsis sp., and Enteromorpha pr., respectively). Extraction of the oil using dichloromethane led to the highest biocrude oil yield (dry biomass) for Chlorella sp. (48.8%), toluene for Nannochloropsis sp. (23.3%), and acetone for Enteromorpha pr. (9.8%). The solvent selection led to a maximum variation of 20.4% for all oil yields. Dichloromethane produced high energy recovery values (maximum: 67.1%) and low energy consumption ratios (minimum: 0.06) regardless of the feedstock chemical composition. Dichloromethane also led to consistently high net energy values and high fossil energy ratios amongst all feedstocks. We speculate that the solvent polarity, chemical structure, hydrogen bonding, and dipole-dipole interactions influenced output parameters by the selective isolation and extraction of the chemical compounds in the biocrude oil. This study suggested that the extraction solvent selection should be carefully considered and normalized for the reporting of hydrothermal liquefaction yields and energy efficiency values.

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  • Watson, Jamison & Lu, Jianwen & de Souza, Raquel & Si, Buchun & Zhang, Yuanhui & Liu, Zhidan, 2019. "Effects of the extraction solvents in hydrothermal liquefaction processes: Biocrude oil quality and energy conversion efficiency," Energy, Elsevier, vol. 167(C), pages 189-197.
    • Handle: RePEc:eee:energy:v:167:y:2019:i:c:p:189-197
    DOI: 10.1016/j.energy.2018.11.003
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    1. Chen, Wan-Ting & Zhang, Yuanhui & Zhang, Jixiang & Schideman, Lance & Yu, Guo & Zhang, Peng & Minarick, Mitchell, 2014. "Co-liquefaction of swine manure and mixed-culture algal biomass from a wastewater treatment system to produce bio-crude oil," Applied Energy, Elsevier, vol. 128(C), pages 209-216.
    2. Jena, Umakanta & Das, K.C. & Kastner, J.R., 2012. "Comparison of the effects of Na2CO3, Ca3(PO4)2, and NiO catalysts on the thermochemical liquefaction of microalga Spirulina platensis," Applied Energy, Elsevier, vol. 98(C), pages 368-375.
    3. Yang, Jie & He, Quan (Sophia) & Niu, Haibo & Corscadden, Kenneth & Astatkie, Tess, 2018. "Hydrothermal liquefaction of biomass model components for product yield prediction and reaction pathways exploration," Applied Energy, Elsevier, vol. 228(C), pages 1618-1628.
    4. Zhu, Zhe & Rosendahl, Lasse & Toor, Saqib Sohail & Yu, Donghong & Chen, Guanyi, 2015. "Hydrothermal liquefaction of barley straw to bio-crude oil: Effects of reaction temperature and aqueous phase recirculation," Applied Energy, Elsevier, vol. 137(C), pages 183-192.
    5. Dincer, Ibrahim & Rosen, Marc A., 2005. "Thermodynamic aspects of renewables and sustainable development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 9(2), pages 169-189, April.
    6. Edward Frank & Amgad Elgowainy & Jeongwoo Han & Zhichao Wang, 2013. "Life cycle comparison of hydrothermal liquefaction and lipid extraction pathways to renewable diesel from algae," Mitigation and Adaptation Strategies for Global Change, Springer, vol. 18(1), pages 137-158, January.
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