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Studies on dynamic responses and impedance of the vanadium redox flow battery

Author

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  • Li, Yifeng
  • Bao, Jie
  • Skyllas-Kazacos, Maria
  • Akter, Md Parvez
  • Zhang, Xinan
  • Fletcher, John

Abstract

This paper studies the feasibility of using the vanadium redox flow battery (VRB) for power quality control applications. This work investigates the dynamic voltage and current responses of the VRB to load changes over a range of frequencies (up to 5 kHz), through experimental studies on a laboratory scale testing system. Experiments were carried out under different operating conditions to examine the effects of system SOC, discharging current and temperature. The analysis shows that the magnitude of battery impedance is higher at low frequencies but lower at high frequencies. These results suggest that the VRB has the ability to handle charging-discharging power fluctuations in a frequency range up to a kHz level. By using the concept of fractional order systems, the transient behaviour of the VRB cell was modelled as an equivalent circuit that utilises a constant phase element to represent the electrochemical double layer and a Warburg element to describe the effect of concentration polarisation. This equivalent circuit model is useful for electrical interface design and power flow control applications.

Suggested Citation

  • Li, Yifeng & Bao, Jie & Skyllas-Kazacos, Maria & Akter, Md Parvez & Zhang, Xinan & Fletcher, John, 2019. "Studies on dynamic responses and impedance of the vanadium redox flow battery," Applied Energy, Elsevier, vol. 237(C), pages 91-102.
    • Handle: RePEc:eee:appene:v:237:y:2019:i:c:p:91-102
    DOI: 10.1016/j.apenergy.2019.01.015
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    References listed on IDEAS

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    1. Mu, Hao & Xiong, Rui & Zheng, Hongfei & Chang, Yuhua & Chen, Zeyu, 2017. "A novel fractional order model based state-of-charge estimation method for lithium-ion battery," Applied Energy, Elsevier, vol. 207(C), pages 384-393.
    2. Fares, Robert L. & Meyers, Jeremy P. & Webber, Michael E., 2014. "A dynamic model-based estimate of the value of a vanadium redox flow battery for frequency regulation in Texas," Applied Energy, Elsevier, vol. 113(C), pages 189-198.
    3. Zheng, Qiong & Li, Xianfeng & Cheng, Yuanhui & Ning, Guiling & Xing, Feng & Zhang, Huamin, 2014. "Development and perspective in vanadium flow battery modeling," Applied Energy, Elsevier, vol. 132(C), pages 254-266.
    4. Wei, Zhongbao & Lim, Tuti Mariana & Skyllas-Kazacos, Maria & Wai, Nyunt & Tseng, King Jet, 2016. "Online state of charge and model parameter co-estimation based on a novel multi-timescale estimator for vanadium redox flow battery," Applied Energy, Elsevier, vol. 172(C), pages 169-179.
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    Cited by:

    1. Guarnieri, Massimo & Trovò, Andrea & Picano, Francesco, 2020. "Enhancing the efficiency of kW-class vanadium redox flow batteries by flow factor modulation: An experimental method," Applied Energy, Elsevier, vol. 262(C).

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