IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v231y2018icp1-11.html
   My bibliography  Save this article

Cross-influence of toluene as tar model compound and HCl on Solid Oxide Fuel Cell anodes in Integrated Biomass Gasifier SOFC Systems

Author

Listed:
  • Cavalli, A.
  • Kunze, M.
  • Aravind, P.V.

Abstract

Integrated Biomass Gasifier Solid Oxide Fuel Cell Systems represent an alternative to fossil fuel based power plants, and direct internal tar reforming allows achieving high efficiency and decreasing system complexity. However, at present, tar is removed or reformed externally since there is not yet general agreement on the fate of these compounds in the anode chamber, and no information is available on the combined effects of tar and other biosyngas contaminants. In this paper, we present the results of short-term experiments on the cross-influence of HCl and tar on Ni-GDC Solid Oxide Fuel Cell anode and on direct internal tar reforming. Initially, the cell was fed with humidified hydrogen and an increasing concentration of HCl (8, 42 and 82 ppmv) and toluene (2.5, 4.2 and 8.4 g/Nm3) separately. Successively, 8.4 g/Nm3 of toluene and an increasing concentration of HCl were fed to the cell. We used polarisation and power density curves, and outlet gas composition analysis to evaluate the contaminants effects. The presence of HCl and toluene caused only a marginal increase in the cell Area Specific Resistance (around 1.5% when the cell was operated at Open Circuit), and the Area Specific Resistance remained then constant during the exposure time. However, HCl affects tar reforming decreasing the concentration of CO2 and CO at the cell outlet. The results indicate the feasibility of direct internal toluene reforming and suggest the revision of currently used tolerance limits based on contaminants cross-influence effects. Extensive research on this topic is still required.

Suggested Citation

  • Cavalli, A. & Kunze, M. & Aravind, P.V., 2018. "Cross-influence of toluene as tar model compound and HCl on Solid Oxide Fuel Cell anodes in Integrated Biomass Gasifier SOFC Systems," Applied Energy, Elsevier, vol. 231(C), pages 1-11.
    • Handle: RePEc:eee:appene:v:231:y:2018:i:c:p:1-11
    DOI: 10.1016/j.apenergy.2018.09.060
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261918313680
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2018.09.060?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Papurello, Davide & Lanzini, Andrea & Drago, Davide & Leone, Pierluigi & Santarelli, Massimo, 2016. "Limiting factors for planar solid oxide fuel cells under different trace compound concentrations," Energy, Elsevier, vol. 95(C), pages 67-78.
    2. Liu, Ming & van der Kleij, A. & Verkooijen, A.H.M. & Aravind, P.V., 2013. "An experimental study of the interaction between tar and SOFCs with Ni/GDC anodes," Applied Energy, Elsevier, vol. 108(C), pages 149-157.
    3. Papurello, Davide & Lanzini, Andrea & Leone, Pierluigi & Santarelli, Massimo, 2016. "The effect of heavy tars (toluene and naphthalene) on the electrochemical performance of an anode-supported SOFC running on bio-syngas," Renewable Energy, Elsevier, vol. 99(C), pages 747-753.
    4. Cinti, Giovanni & Desideri, Umberto, 2015. "SOFC fuelled with reformed urea," Applied Energy, Elsevier, vol. 154(C), pages 242-253.
    5. Caposciutti, Gianluca & Barontini, Federica & Antonelli, Marco & Tognotti, Leonardo & Desideri, Umberto, 2018. "Experimental investigation on the air excess and air displacement influence on early stage and complete combustion gaseous emissions of a small scale fixed bed biomass boiler," Applied Energy, Elsevier, vol. 216(C), pages 576-587.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Subotić, Vanja & Baldinelli, Arianna & Barelli, Linda & Scharler, Robert & Pongratz, Gernot & Hochenauer, Christoph & Anca-Couce, Andrés, 2019. "Applicability of the SOFC technology for coupling with biomass-gasifier systems: Short- and long-term experimental study on SOFC performance and degradation behaviour," Applied Energy, Elsevier, vol. 256(C).
    2. Luca Del Zotto & Andrea Monforti Ferrario & Arda Hatunoglu & Alessandro Dell’Era & Stephen McPhail & Enrico Bocci, 2021. "Experimental Procedures & First Results of an Innovative Solid Oxide Fuel Cell Test Rig: Parametric Analysis and Stability Test," Energies, MDPI, vol. 14(8), pages 1-19, April.
    3. Ouyang, Tiancheng & Zhang, Mingliang & Qin, Peijia & Liu, Wenjun & Shi, Xiaomin, 2022. "Converting waste into electric energy and carbon fixation through biosyngas-fueled SOFC hybrid system: A simulation study," Renewable Energy, Elsevier, vol. 193(C), pages 725-743.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Papurello, Davide & Chiodo, Vitaliano & Maisano, Susanna & Lanzini, Andrea & Santarelli, Massimo, 2018. "Catalytic stability of a Ni-Catalyst towards biogas reforming in the presence of deactivating trace compounds," Renewable Energy, Elsevier, vol. 127(C), pages 481-494.
    2. Choi, Young-Kon & Mun, Tae-Young & Cho, Min-Hwan & Kim, Joo-Sik, 2016. "Gasification of dried sewage sludge in a newly developed three-stage gasifier: Effect of each reactor temperature on the producer gas composition and impurity removal," Energy, Elsevier, vol. 114(C), pages 121-128.
    3. Papurello, Davide & Iafrate, Chiara & Lanzini, Andrea & Santarelli, Massimo, 2017. "Trace compounds impact on SOFC performance: Experimental and modelling approach," Applied Energy, Elsevier, vol. 208(C), pages 637-654.
    4. Papurello, Davide & Boschetti, Andrea & Silvestri, Silvia & Khomenko, Iuliia & Biasioli, Franco, 2018. "Real-time monitoring of removal of trace compounds with PTR-MS: Biochar experimental investigation," Renewable Energy, Elsevier, vol. 125(C), pages 344-355.
    5. Mehrpooya, Mehdi & Sharifzadeh, Mohammad Mehdi Moftakhari, 2017. "Conceptual and basic design of a novel integrated cogeneration power plant energy system," Energy, Elsevier, vol. 127(C), pages 516-533.
    6. Giovanni Coppola & Davide Papurello, 2018. "Biogas Cleaning: Activated Carbon Regeneration for H 2 S Removal," Clean Technol., MDPI, vol. 1(1), pages 1-18, June.
    7. Davide Papurello & Massimo Santarelli & Sonia Fiorilli, 2018. "Physical Activation of Waste-Derived Materials for Biogas Cleaning," Energies, MDPI, vol. 11(9), pages 1-12, September.
    8. Papurello, Davide & Lanzini, Andrea & Leone, Pierluigi & Santarelli, Massimo, 2016. "The effect of heavy tars (toluene and naphthalene) on the electrochemical performance of an anode-supported SOFC running on bio-syngas," Renewable Energy, Elsevier, vol. 99(C), pages 747-753.
    9. Sharma, Monikankana & N, Rakesh & Dasappa, S., 2016. "Solid oxide fuel cell operating with biomass derived producer gas: Status and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 450-463.
    10. Tanveer, Waqas Hassan & Rezk, Hegazy & Nassef, Ahmed & Abdelkareem, Mohammad Ali & Kolosz, Ben & Karuppasamy, K. & Aslam, Jawad & Gilani, Syed Omer, 2020. "Improving fuel cell performance via optimal parameters identification through fuzzy logic based-modeling and optimization," Energy, Elsevier, vol. 204(C).
    11. Yu, Fangyong & Xiao, Jie & Zhang, Yapeng & Cai, Weizi & Xie, Yongmin & Yang, Naitao & Liu, Jiang & Liu, Meilin, 2019. "New insights into carbon deposition mechanism of nickel/yttrium-stabilized zirconia cermet from methane by in situ investigation," Applied Energy, Elsevier, vol. 256(C).
    12. Roberto Paglini & Marta Gandiglio & Andrea Lanzini, 2022. "Technologies for Deep Biogas Purification and Use in Zero-Emission Fuel Cells Systems," Energies, MDPI, vol. 15(10), pages 1-30, May.
    13. Zhang, Hanfei & Wang, Ligang & Van herle, Jan & Maréchal, François & Desideri, Umberto, 2021. "Techno-economic comparison of 100% renewable urea production processes," Applied Energy, Elsevier, vol. 284(C).
    14. Dang, Zheng & Xu, Han, 2016. "Pore scale investigation of gaseous mixture flow in porous anode of solid oxide fuel cell," Energy, Elsevier, vol. 107(C), pages 295-304.
    15. Kupecki, Jakub & Papurello, Davide & Lanzini, Andrea & Naumovich, Yevgeniy & Motylinski, Konrad & Blesznowski, Marcin & Santarelli, Massimo, 2018. "Numerical model of planar anode supported solid oxide fuel cell fed with fuel containing H2S operated in direct internal reforming mode (DIR-SOFC)," Applied Energy, Elsevier, vol. 230(C), pages 1573-1584.
    16. Ud Din, Zia & Zainal, Z.A., 2016. "Biomass integrated gasification–SOFC systems: Technology overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 1356-1376.
    17. Bargiacchi, Eleonora & Antonelli, Marco & Desideri, Umberto, 2019. "A comparative assessment of Power-to-Fuel production pathways," Energy, Elsevier, vol. 183(C), pages 1253-1265.
    18. Chen, Jinwei & Hu, Zhenchao & Lu, Jinzhi & Zhang, Huisheng & Weng, Shilie, 2022. "A novel control strategy with an anode variable geometry ejector for a SOFC-GT hybrid system," Energy, Elsevier, vol. 261(PA).
    19. Yan, Dong & Zhang, Chi & Liang, Linjiang & Li, Kai & Jia, Lichao & Pu, Jian & Jian, Li & Li, Xi & Zhang, Tao, 2016. "Degradation analysis and durability improvement for SOFC 1-cell stack," Applied Energy, Elsevier, vol. 175(C), pages 414-420.
    20. Chen, Qianyang & Qiu, Qianyuan & Yan, Xiaomin & Zhou, Mingyang & Zhang, Yapeng & Liu, Zhijun & Cai, Weizi & Wang, Wei & Liu, Jiang, 2020. "A compact and seal-less direct carbon solid oxide fuel cell stack stepping into practical application," Applied Energy, Elsevier, vol. 278(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:231:y:2018:i:c:p:1-11. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.