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Study on reduction and carburization behaviors of iron phases for iron-based Fischer–Tropsch synthesis catalyst

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  • Ding, Mingyue
  • Yang, Yong
  • Wu, Baoshan
  • Li, Yongwang
  • Wang, Tiejun
  • Ma, Longlong

Abstract

Reduction and carburization behaviors of iron phases over a precipitated iron-based Fischer–Tropsch synthesis (FTS) catalyst were investigated by some techniques of Mössbauer effect spectroscopy (MES), X-ray photoelectron spectroscopy (XPS) and diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) as well as H2&CO temperature-programmed desorption (H2&CO-TPD). It was found that in H2 atmosphere phase transformation of iron phases involved α-Fe2O3→Fe3O4→FeO→α-Fe, both occurring in the bulk and on the surface layers. All of reduced iron species took place the carburization reaction, whereas carburizing ability was following the order α-Fe>FeO>Fe3O4. During FTS both iron carbides and Fe(II) oxide species reached a balance state without appearing the intermediate α-Fe. The conversion of reduced iron phases to iron carbides (especially for χ-Fe5C2) on the surface layers played a positive role in promoting the formation of hydrocarbons species.

Suggested Citation

  • Ding, Mingyue & Yang, Yong & Wu, Baoshan & Li, Yongwang & Wang, Tiejun & Ma, Longlong, 2015. "Study on reduction and carburization behaviors of iron phases for iron-based Fischer–Tropsch synthesis catalyst," Applied Energy, Elsevier, vol. 160(C), pages 982-989.
    • Handle: RePEc:eee:appene:v:160:y:2015:i:c:p:982-989
    DOI: 10.1016/j.apenergy.2014.12.042
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    References listed on IDEAS

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    1. Rahimpour, M.R. & Bahmanpour, A.M., 2011. "Optimization of hydrogen production via coupling of the Fischer-Tropsch synthesis reaction and dehydrogenation of cyclohexane in GTL technology," Applied Energy, Elsevier, vol. 88(6), pages 2027-2036, June.
    2. DiGenova, Kevin J. & Botros, Barbara B. & Brisson, J.G., 2013. "Method for customizing an organic Rankine cycle to a complex heat source for efficient energy conversion, demonstrated on a Fischer Tropsch plant," Applied Energy, Elsevier, vol. 102(C), pages 746-754.
    3. Ding, Mingyue & Yang, Yong & Li, Yongwang & Wang, Tiejun & Ma, Longlong & Wu, Chuangzhi, 2013. "Impact of H2/CO ratios on phase and performance of Mn-modified Fe-based Fischer Tropsch synthesis catalyst," Applied Energy, Elsevier, vol. 112(C), pages 1241-1246.
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    Cited by:

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    2. Galadima, Ahmad & Muraza, Oki, 2019. "Catalytic thermal conversion of CO2 into fuels: Perspective and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 115(C).

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