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Optimal Open-Loop Recipe Generation For Particle Size Distribution Control In Semi-Batch Emulsion Polymerisation

In: Computer Aided Methods In Optimal Design And Operations

Author

Listed:
  • N. BIANCO

    (Department of Chemical Engineering, Centre for Process System Engineering, Imperial College London, London SW7 2AZ, UK)

  • C. D. IMMANUEL

    (Department of Chemical Engineering, Centre for Process System Engineering, Imperial College London, London SW7 2AZ, UK)

Abstract

Emulsion polymerisation is widely used in industry to produce a large range of products. Many important properties of the polymer products are strongly influenced by the particle size distribution (PSD) of the latex. PSD is driven by three major phenomena: particle nucleation, growth and coagulation, each of which strongly interact with each other, present irreversible traits and have widely different time constants, thereby rendering PSD control challenging. In this study a population balance model is used to develop feed policy to attain target PSD. A multi-objective optimisation strategy that targets the individual phenomena of nucleation, growth and coagulation is adopted.

Suggested Citation

  • N. Bianco & C. D. Immanuel, 2006. "Optimal Open-Loop Recipe Generation For Particle Size Distribution Control In Semi-Batch Emulsion Polymerisation," World Scientific Book Chapters, in: I D L Bogle & J Žilinskas (ed.), Computer Aided Methods In Optimal Design And Operations, chapter 11, pages 99-108, World Scientific Publishing Co. Pte. Ltd..
  • Handle: RePEc:wsi:wschap:9789812772954_0011
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