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Quantum-Chemical Models of the Active Centres of Transition Metals Biologically Active Complexes. Interconnection of the Active Centres Structure and the Functions

In: Mathematical Models of Non-Linear Excitations, Transfer, Dynamics, and Control in Condensed Systems and Other Media

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  • Ludmila Yu. Vasil’eva

    (Tver’ State University)

Abstract

Biologically active complexes containing transition metal ions take part in the metabolism processes. The following conclusions were arisen from the structure analysis of the simple metalloenzymes and more complicated complexes: 1) such systems have much in common in the active centres structure though performing different functions; 2) the acctive centres stereochemistry is determined by the electronic configuration of the central ions and the nature of the ligands; 3) interactions between the central ions and the ligands have a donor-acceptor nature: the metal ions give for the bond the vacant binding sites (unoccupied orbitals) and the peptide nitrogen or oxygen — the lone electron pairs.

Suggested Citation

  • Ludmila Yu. Vasil’eva, 1999. "Quantum-Chemical Models of the Active Centres of Transition Metals Biologically Active Complexes. Interconnection of the Active Centres Structure and the Functions," Springer Books, in: Ludmila A. Uvarova & Arkadii E. Arinstein & Anatolii V. Latyshev (ed.), Mathematical Models of Non-Linear Excitations, Transfer, Dynamics, and Control in Condensed Systems and Other Media, pages 385-398, Springer.
    • Handle: RePEc:spr:sprchp:978-1-4615-4799-0_31
    DOI: 10.1007/978-1-4615-4799-0_31
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