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Structural Aspects of Iodine-Containing Low-Dimensional Materials

In: Extended Linear Chain Compounds

Author

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  • Philip Coppens

    (State University of New York, Department of Chemistry)

Abstract

This chapter concerns the structural aspects of iodine-containing low-dimensional solids with particular emphasis on the arrangement of the iodine atoms. Many of the solids under consideration are cation radical salts with a high anisotropic conductivity. An impressive variety of cations occurs, ranging from transition metal complexes like Ni(dpg)2, Ni(bqd)2 and Pd(bqd)2 (dpg = diphenylglyoxime; bqd = 1,2-benzoquinonedigly-oxime) to organic molecules like tetrathiotetracene, trimesic acid, and perylene. Most known phases are binary, but multicomponent systems such as TMA+TCNQ2/3−(I3 −)1/3 (TMA = trimethylammonium, N(CH3)3H+; TCNQ = 7,7,8,8-tetracyano-p-quinodimethane) and K2Bz9I9·CHCl3(Bz = benzophenone) offer further variation in structural and physical properties. Though the conductivity process is frequently electronic, it appears predominantly ionic in the alkali-iodine-benzophenone complexes.1

Suggested Citation

  • Philip Coppens, 1982. "Structural Aspects of Iodine-Containing Low-Dimensional Materials," Springer Books, in: Joel S. Miller (ed.), Extended Linear Chain Compounds, chapter 7, pages 333-356, Springer.
    • Handle: RePEc:spr:sprchp:978-1-4613-3249-7_7
    DOI: 10.1007/978-1-4613-3249-7_7
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