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FLOWER-LIKE NANOPARTICLES OFPt–BiIIIASSEMBLED ON AGMATINE SULFATE MODIFIED GLASSY CARBON ELECTRODE AND THEIR ELECTROCATALYSIS OFH2O2

Author

Listed:
  • MINGSHU XIAO

    (University of Shanghai for Science and Technology, Shanghai 200093, P. R. China)

  • YUHUA YAN

    (University of Shanghai for Science and Technology, Shanghai 200093, P. R. China)

  • KAI FENG

    (University of Shanghai for Science and Technology, Shanghai 200093, P. R. China)

  • YANPING TIAN

    (University of Shanghai for Science and Technology, Shanghai 200093, P. R. China)

  • YUQING MIAO

    (University of Shanghai for Science and Technology, Shanghai 200093, P. R. China)

Abstract

A new electrochemical technique to detect hydrogen peroxide(H2O2)was developed. ThePtnanoparticles andBiIIIwere subsequently assembled on agmatine sulfate (AS) modified glassy carbon electrode (GCE) and the prepared GCE–AS-Pt–BiIIIwas characterized by scanning electron microscopy (SEM) with result showing that the flower-like nanostructure ofPt–BiIIIwas yielded. Compared withPtnanoparticles, the flower-like nanostructure ofPt–BiIIIgreatly enhanced the electrocatalysis of GCE–AS-Pt–BiIIItowardsH2O2, which is ascribed to morePt–OHobtained on GCE–AS-Pt–BiIIIsurface for the presence ofBiIII. Based on its high electrocatalysis, GCE–AS-Pt–BiIIIwas used to determine the content ofH2O2in the sample of sheet bean curd with standard addition method. Meantime, its electrocatalytic activity also was studied.

Suggested Citation

  • Mingshu Xiao & Yuhua Yan & Kai Feng & Yanping Tian & Yuqing Miao, 2015. "FLOWER-LIKE NANOPARTICLES OFPt–BiIIIASSEMBLED ON AGMATINE SULFATE MODIFIED GLASSY CARBON ELECTRODE AND THEIR ELECTROCATALYSIS OFH2O2," Surface Review and Letters (SRL), World Scientific Publishing Co. Pte. Ltd., vol. 22(03), pages 1-7.
  • Handle: RePEc:wsi:srlxxx:v:22:y:2015:i:03:n:s0218625x15500432
    DOI: 10.1142/S0218625X15500432
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    Keywords

    Pt–BiIII; H2O2; electrocatalysis; flower-like;
    All these keywords.

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