Author
Listed:
- MIN-KYUNG KIM
(Department of Polymer Science and Engineering, Pusan National University, San30, Jangeon-Dong, Gumjeong-Gu, Busan 609-735, Korea)
- YU-JIN LEE
(Department of Polymer Science and Engineering, Pusan National University, San30, Jangeon-Dong, Gumjeong-Gu, Busan 609-735, Korea)
- NAM-JU JO
(Department of Polymer Science and Engineering, Pusan National University, San30, Jangeon-Dong, Gumjeong-Gu, Busan 609-735, Korea)
Abstract
To obtain high ambient ionic conductivity of solid polymer electrolyte (SPE), we introduce polymer-in-salt system with ion hopping mechanism contrary to traditional salt-in-polymer system with segmental motion mechanism. In polymer-in-salt system, the interaction between polymer and salt is important because polymer-in-salt electrolyte contains a large amount of salt. Thus, we try to solve the origin of interaction between polymer and salt by using hard/soft acid base (HSAB) principle. The SPEs are made up of two types of polymers (poly(ethylene oxide) (PEO, hard base) and poly(ethylene imine) (PEI, softer base than PEO)) and four types of salts (LiCF3SO3(hard cation/hard anion),LiCl(hard cation/soft anion),AgCF3SO3(soft cation/hard anion), andAgCl(soft cation/soft anion)) according to HSAB principle. In salt-in-polymer system, ionic conductivities of SPEs were affected by HSAB principle but in polymer-in-salt system, they were influenced by the ion hopping property of salt rather than the solubility of polymer for salt according to HSAB principle. The highest ionic conductivities of PEO-based and PEI-based SPEs were 5.13 × 10-4Scm-1and 7.32 × 10-4Scm-1in polymer-in-salt system, respectively.
Suggested Citation
Min-Kyung Kim & Yu-Jin Lee & Nam-Ju Jo, 2010.
"The Effect Of Hsab Principle On Electrochemical Properties Of Polymer-In-Salt Electrolytes With Aliphatic Polymer,"
Surface Review and Letters (SRL), World Scientific Publishing Co. Pte. Ltd., vol. 17(01), pages 63-68.
Handle:
RePEc:wsi:srlxxx:v:17:y:2010:i:01:n:s0218625x10013825
DOI: 10.1142/S0218625X10013825
Download full text from publisher
As the access to this document is restricted, you may want to
for a different version of it.
Corrections
All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:wsi:srlxxx:v:17:y:2010:i:01:n:s0218625x10013825. See general information about how to correct material in RePEc.
If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.
We have no bibliographic references for this item. You can help adding them by using this form .
If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.
For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Tai Tone Lim (email available below). General contact details of provider: http://www.worldscinet.com/srl/srl.shtml .
Please note that corrections may take a couple of weeks to filter through
the various RePEc services.