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ELECTROCHEMICAL PERFORMANCE OF MICROBATTERIES USING CRYSTALLIZEDLiCoO2AND NANO-CRYSTALLINELiMn2O4FILM AS CATHODES AND AMORPHOUSLiNiVO4AS ANODE

Author

Listed:
  • S. B. TANG

    (Department of Mechanical Engineering, National University of Singapore, Singapore 117576, Singapore)

  • M. O. LAI

    (Department of Mechanical Engineering, National University of Singapore, Singapore 117576, Singapore)

  • L. LU

    (Department of Mechanical Engineering, National University of Singapore, Singapore 117576, Singapore)

Abstract

Three different electrode films of highly crystallizedLiCoO2, nano-crystallineLiMn2O4as cathode and amorphousLiNiVO4as anode were grown on stainless steel substrates by pulsed laser deposition. Microbatteries were assembled using liquid electrode ofLiPF6. The microbatteries were electrochemically tested by charge/discharge cycling and cyclic voltammetry. BothLiCoO2/LiPF6/LiNiVO4andLiMn2O4/LiPF6/LiNiVO4cells showed smooth charge/discharge curves. Although the cells faced a fast capacity loss in the first 10 cycles, about 20 μA/cm2μm of discharge capacity was attainable after 20 cycles.

Suggested Citation

  • S. B. Tang & M. O. Lai & L. Lu, 2008. "ELECTROCHEMICAL PERFORMANCE OF MICROBATTERIES USING CRYSTALLIZEDLiCoO2AND NANO-CRYSTALLINELiMn2O4FILM AS CATHODES AND AMORPHOUSLiNiVO4AS ANODE," Surface Review and Letters (SRL), World Scientific Publishing Co. Pte. Ltd., vol. 15(01n02), pages 169-174.
  • Handle: RePEc:wsi:srlxxx:v:15:y:2008:i:01n02:n:s0218625x08011160
    DOI: 10.1142/S0218625X08011160
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