Author
Listed:
- MI NA PARK
(Department of Chemistry, Pukyong National University, Daeyeon-3-dong, Nam-gu, Busan 608737, Korea)
- YOUNG SOO KANG
(Department of Chemistry, Pukyong National University, Daeyeon-3-dong, Nam-gu, Busan 608737, Korea)
- SUN WHA OH
(Basic Science Research Institute, Pukyong National University, 599-1 Daeyeon 3-dong, Nam-gu, Busan 608737, Korea)
- BYUNG HYUN AHN
(School of Material Science and Engineering, Pukyong National University, San 100, Yongdang-Dong, Nam-gu, Busan 608739, Korea)
- MYUNG JUN MOON
(Department of Industrial Chemistry, Pukyong National University, Sam 100, Yongdang-Dang, Nam-gu, Busan 608739, Korea)
Abstract
The single hydroxyl-terminated urethane acrylate oligomers were synthesized from 2-mercaptoethanol (2-MEOH), alkyl (methyl, butyl, and 2-ethylhexyl) acrylate, and 2,2-azobisisobutyronitrile (AIBN, initiator), with dibutyltin dilaurate (DBTDL) as a catalyst. 2-MEOH was used as a functional chain transfer agent. Poly(alkyl urethane) acrylate oligomers were obtained by the reaction of single hydroxyl-terminated polyalkyl acrylates and 2-isocyanatoethyl acrylate. They were characterized by NMR, FT-IR spectroscopy, rheometer, and DSC. Because poly(alkyl urethane) acrylate oligomers have lowerTgand viscosity than hydroxyl-terminated polyalkyl acrylate oligomers (HTPAO) non-containing urethane groups, they can be used for ultraviolet (UV) curable coatings, inks, and adhesives.
Suggested Citation
Mi Na Park & Young Soo Kang & Sun Wha Oh & Byung Hyun Ahn & Myung Jun Moon, 2007.
"Synthesis And Characterization Of Polyurethane Acrylates For Uv Curable Coating Agents,"
Surface Review and Letters (SRL), World Scientific Publishing Co. Pte. Ltd., vol. 14(04), pages 713-717.
Handle:
RePEc:wsi:srlxxx:v:14:y:2007:i:04:n:s0218625x07009980
DOI: 10.1142/S0218625X07009980
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