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PHOTOELECTRONIC INVESTIGATION OFPdELECTRON STRUCTURE TRANSFORMATION AT OXYGEN ADSORPTION

Author

Listed:
  • V. P. BELASH

    (Physical-Technical Institute, Ural Branch, Russian Academy of Sciences, Izhevsk, Udmurt Republic 426008, Russia)

  • I. N. KLIMOVA

    (Physical-Technical Institute, Ural Branch, Russian Academy of Sciences, Izhevsk, Udmurt Republic 426008, Russia)

  • Yu. S. MITROKHIN

    (Department of Mathematics, Udmurt State University, Izhevsk, Udmurt Republic 426034, Russia)

Abstract

Oxygen adsorption on the surface of polycrystalline palladium has been studied by the photoelectron spectroscopy method in a wide range of oxygen exposure and temperatures, starting with the earliest stages of adsorption to the formation of the surface compound ofPdO-type. Based on the analysis of the experimental data and the calculation of the density of states carried out by the TB-LMTO-ASA method, the attempt to elucidate the electronic mechanism of adsorption and oxidation power of palladium was made.

Suggested Citation

  • V. P. BELASH & I. N. KLIMOVA & Yu. S. MITROKHIN, 2005. "PHOTOELECTRONIC INVESTIGATION OFPdELECTRON STRUCTURE TRANSFORMATION AT OXYGEN ADSORPTION," Surface Review and Letters (SRL), World Scientific Publishing Co. Pte. Ltd., vol. 12(05n06), pages 713-719.
  • Handle: RePEc:wsi:srlxxx:v:12:y:2005:i:05n06:n:s0218625x05007980
    DOI: 10.1142/S0218625X05007980
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