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THE LOW COVERAGE PHASES OF PbON Ge(001): SCANNING TUNNELING MICROSCOPY AND FIRST PRINCIPLES

Author

Listed:
  • NOBORU TAKEUCHI

    (Centro de Ciencias de la Materia Condensada, Universidad Nacional Autónoma de México, Apartado Postal 2681, Ensenada, Baja California, 22800, Mexico)

  • G. FALKENBERG

    (II. Institut fur Experimentalphysick Universitat Hamburg, Luruper Chausse 149, D-22761, Hamburg, Germany)

  • R. L. JOHNSON

    (II. Institut fur Experimentalphysick Universitat Hamburg, Luruper Chausse 149, D-22761, Hamburg, Germany)

Abstract

Using scanning tunneling microscopy and first principles total energy calculations, we have studied the atomic structure of the low coverage phases of Pb on Ge(001): the(2 × 2)and thec(4 × 8)- αreconstructions. Based on the analysis of the experimental bias-dependent STM images and supported by theab initiopseudopotential density-functional calculations, we present models for each structure. In both cases, there is a coexistence of Ge and Pb dimers. The(2 × 2)phase is formed by asymmetric Pb dimers parallel and in the trenches between the underlying Ge dimers. The Pb coverage is 0.5 ML and it corresponds to the maximum packing density of Pb dimers without breaking Ge dimers. Thec(4 × 8) - αreconstruction has a Pb coverage of 0.75 ML and it is characterized by asymmetric Pb dimers forming chains along the [110] direction. However, in this case half of the Ge dimers are broken. The other half remain intact and they are perpendicular to the Pb dimers.

Suggested Citation

  • Noboru Takeuchi & G. Falkenberg & R. L. Johnson, 2002. "THE LOW COVERAGE PHASES OF PbON Ge(001): SCANNING TUNNELING MICROSCOPY AND FIRST PRINCIPLES," Surface Review and Letters (SRL), World Scientific Publishing Co. Pte. Ltd., vol. 9(05n06), pages 1809-1814.
  • Handle: RePEc:wsi:srlxxx:v:09:y:2002:i:05n06:n:s0218625x02004499
    DOI: 10.1142/S0218625X02004499
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