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STUDY OF MICROSTRUCTURE AND CATALYTIC ACTIVITY OFγ-Bi2MoO6ANDBi2WO6COMPOUNDS

Author

Listed:
  • R. RANGEL

    (Facultad de Ingeniería Química, Universidad Michoacana de SNH, Edificio "K" Ciudad Universitaria, 58060, Morelia, Mich., Mexico)

  • P. BARTOLO-PÉREZ

    (Departamento de Física Aplicada, Centro de Investigación y de Estudios Avanzados del IPN, Apartado Postal 73 Cordemex, 97310, Mérida, Yucatán, Mexico)

  • A. GÓMEZ-CORTÉZ

    (Instituto de Física, Universidad Nacional Autónoma de México, Apartado Postal 20-364, 01000, Mexico, DF, Mexico)

  • G. DÍAZ

    (Instituto de Física, Universidad Nacional Autónoma de México, Apartado Postal 20-364, 01000, Mexico, DF, Mexico)

  • D. H. GALVÁN

    (Centro de Ciencias de la Materia Condensada, Universidad Nacional Autónoma de México, Apartado Postal 2681, 22800, Ensenada, BC, Mexico)

Abstract

Bi2MO6(M=Mo, W) compounds were prepared for low-temperature oxidation. The catalysts were prepared by solid-state reaction. The structural changes were followed by X-ray diffraction, scanning electron microscopy, Auger electron spectroscopy and BET nitrogen absorption. Auger analysis shows thatBi2WO6catalysts have more bismuth on the surface thanγ-Bi2MoO6, although both samples are bismuth deficient as compared to the stoichiometric compound. The results regarding catalytic activity show thatBi2WO6prepared at 1073 K reaches total conversion of CO (100%) at a lower temperature when compared toγ-Bi2MoO6. This indicates thatBi2WO6is a potential candidate to be used as catalyst in the CO toCO2oxidation.

Suggested Citation

  • R. Rangel & P. Bartolo-Pérez & A. Gómez-Cortéz & G. Díaz & D. H. Galván, 2002. "STUDY OF MICROSTRUCTURE AND CATALYTIC ACTIVITY OFγ-Bi2MoO6ANDBi2WO6COMPOUNDS," Surface Review and Letters (SRL), World Scientific Publishing Co. Pte. Ltd., vol. 9(05n06), pages 1779-1783.
  • Handle: RePEc:wsi:srlxxx:v:09:y:2002:i:05n06:n:s0218625x02004402
    DOI: 10.1142/S0218625X02004402
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