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Interfacial Oxide Layers At The Metal–Oxide Phase Boundary

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  • FALKO P. NETZER

    (Institut für Experimentalphysik, Karl-Franzens-Universität Graz, A-8010 Graz, Austria)

Abstract

The nature of oxide phases at metal–oxide interfaces, i.e. of oxide layers in the proximity of a metal surface, is assessed by critically examining the available data in the literature. The data reveal a trend towards the formation of reduced oxide phases with lower oxidation states in the vicinity of the interface with a metal. The physical origin of these interface-stabilized oxide layers is discussed and the possible causes include strong metal–metal bonding, high oxygen affinity of the substrate metal, reduction of the interfacial strain, and the stability of two-dimensional oxide phases.

Suggested Citation

  • Falko P. Netzer, 2002. "Interfacial Oxide Layers At The Metal–Oxide Phase Boundary," Surface Review and Letters (SRL), World Scientific Publishing Co. Pte. Ltd., vol. 9(03n04), pages 1553-1563.
    • Handle: RePEc:wsi:srlxxx:v:09:y:2002:i:03n04:n:s0218625x02003950
    DOI: 10.1142/S0218625X02003950
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