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ELECTRONIC STRUCTURE OFCoSe2

Author

Listed:
  • H. SATO

    (Graduate School of Science, Hiroshima University, Kagamiyama 1-3-1, Higashi-Hiroshima 739-8526, Japan)

  • F. NAGASAKI

    (Graduate School of Science, Hiroshima University, Kagamiyama 1-3-1, Higashi-Hiroshima 739-8526, Japan)

  • Y. KANI

    (Graduate School of Science, Hiroshima University, Kagamiyama 1-3-1, Higashi-Hiroshima 739-8526, Japan)

  • S. SENBA

    (Hiroshima Synchrotron Radiation Center, Hiroshima University, Kagamiyama 2-313, Higashi-Hiroshima 739-8526, Japan)

  • Y. UEDA

    (Kure National College of Technology, Agaminami 2-2-11, Kure 737-8506, Japan)

  • A. KIMURA

    (Graduate School of Science, Hiroshima University, Kagamiyama 1-3-1, Higashi-Hiroshima 739-8526, Japan)

  • M. TANIGUCHI

    (Graduate School of Science, Hiroshima University, Kagamiyama 1-3-1, Higashi-Hiroshima 739-8526, Japan;
    Hiroshima Synchrotron Radiation Center, Hiroshima University, Kagamiyama 2-313, Higashi-Hiroshima 739-8526, Japan)

Abstract

The valence-band and conduction-band electronic structure of pyrite-typeCoSe2has been investigated by means of ultraviolet-photoemission, synchrotron-radiation-photoemission and inverse-photoemission spectroscopies. The fully occupied Co 3d states witht2gsymmetry are observed as a main peak at -1.0 eV relative to the Fermi level(EF), and the partially filled Co 3d states withegsymmetry are observed as a shoulder at theEFside of the main peak. On the other hand, the structure due to the unoccupied Coegstates appears at 0.6 eV in the inverse-photoemission spectrum. The electronic structure ofCoSe2is similar to that ofCoS2. The electron correlation is more important forCoSe2than forCoS2.

Suggested Citation

  • H. Sato & F. Nagasaki & Y. Kani & S. Senba & Y. Ueda & A. Kimura & M. Taniguchi, 2002. "ELECTRONIC STRUCTURE OFCoSe2," Surface Review and Letters (SRL), World Scientific Publishing Co. Pte. Ltd., vol. 9(02), pages 1315-1319.
  • Handle: RePEc:wsi:srlxxx:v:09:y:2002:i:02:n:s0218625x02003731
    DOI: 10.1142/S0218625X02003731
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