IDEAS home Printed from https://ideas.repec.org/a/wsi/srlxxx/v08y2001i01n02ns0218625x0100094x.html
   My bibliography  Save this article

Oscillations In Catalytic Reactions: Carbon Model With Adsorbate–Adsorbate Lateral Interactions

Author

Listed:
  • V. P. ZHDANOV

Abstract

We present Monte Carlo simulations of kinetic oscillations in CO oxidation on Pt in the framework of the model including carbon deposition on and removal from the catalyst surface. Some of the elementary reaction steps (such as carbon removal and diffusion) are considered to be dependent on adsorbate–adsorbate lateral interactions. The results obtained indicate that the lateral interactions may play a key role in kinetic oscillations. In particular, the interactions may result in the appearance of oscillations and also in their suppression. The former takes place if the interactions form a feedback between the high and low reactive states of the bistable catalytic cycle. The latter may be connected, for example, with the formation of carbon islands on the surface.

Suggested Citation

  • V. P. Zhdanov, 2001. "Oscillations In Catalytic Reactions: Carbon Model With Adsorbate–Adsorbate Lateral Interactions," Surface Review and Letters (SRL), World Scientific Publishing Co. Pte. Ltd., vol. 8(01n02), pages 51-59.
    • Handle: RePEc:wsi:srlxxx:v:08:y:2001:i:01n02:n:s0218625x0100094x
    DOI: 10.1142/S0218625X0100094X
    as

    Download full text from publisher

    File URL: http://www.worldscientific.com/doi/abs/10.1142/S0218625X0100094X
    Download Restriction: Access to full text is restricted to subscribers
    File URL: https://libkey.io/10.1142/S0218625X0100094X?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    More about this item

    Keywords

    ; 05.70Ln; 68.10.Jy; 82.65.Jv;
    All these keywords.

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:wsi:srlxxx:v:08:y:2001:i:01n02:n:s0218625x0100094x. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Tai Tone Lim (email available below). General contact details of provider: http://www.worldscinet.com/srl/srl.shtml .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.