IDEAS home Printed from https://ideas.repec.org/a/wsi/srlxxx/v04y1997i06ns0218625x97001565.html
   My bibliography  Save this article

ADSORPTION SITE CHANGE FORCs,RbORKADSORPTION ONAg(111)

Author

Listed:
  • P. KAUKASOINA

    (Physics Department, Tampere University of Technology, PO Box 692, 33101, Tampere, Finland)

  • M. LINDROOS

    (Physics Department, Tampere University of Technology, PO Box 692, 33101, Tampere, Finland)

  • G. S. LEATHERMAN

    (Physics Department, Penn State University, University Park, PA 16802, USA)

  • R. D. DIEHL

    (Physics Department, Penn State University, University Park, PA 16802, USA)

Abstract

The adsorption geometries for the primitive(3×3), (2×2)and ($\sqrt{3}\times\sqrt{3}{\rm R}30^\circ)$structures of K, Rb and Cs on Ag(111) have been determined using low-energy electron diffraction. In the lower-coverage(3×3)and(2×2)structures, the adatoms occupy fcc hollow sites, while in the$(\sqrt{3}\times\sqrt{3}){\rm R}30^\circ; structure they occupy the hcp hollow sites. The fcc hollow structures are accompanied by significant substrate rumpling. There is no significant coverage-dependent or site-dependent change in chemisorption bond length. However, there is a large coverage-dependent anisotropy of vibrational amplitude of the adatoms, with the parallel component as much as five times larger than the perpendicular component at low coverages.

Suggested Citation

  • P. Kaukasoina & M. Lindroos & G. S. Leatherman & R. D. Diehl, 1997. "ADSORPTION SITE CHANGE FORCs,RbORKADSORPTION ONAg(111)," Surface Review and Letters (SRL), World Scientific Publishing Co. Pte. Ltd., vol. 4(06), pages 1215-1219.
  • Handle: RePEc:wsi:srlxxx:v:04:y:1997:i:06:n:s0218625x97001565
    DOI: 10.1142/S0218625X97001565
    as

    Download full text from publisher

    File URL: http://www.worldscientific.com/doi/abs/10.1142/S0218625X97001565
    Download Restriction: Access to full text is restricted to subscribers

    File URL: https://libkey.io/10.1142/S0218625X97001565?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:wsi:srlxxx:v:04:y:1997:i:06:n:s0218625x97001565. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Tai Tone Lim (email available below). General contact details of provider: http://www.worldscinet.com/srl/srl.shtml .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.