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VALENCE-BAND PHOTOEMISSION STUDY OF(Ba,Cs)onW(110)

Author

Listed:
  • TUN-WEN PI

    (Synchrotron Radiation Research Center, Hsinchu, Taiwan, ROC)

  • LE-HONG HONG

    (Synchrotron Radiation Research Center, Hsinchu, Taiwan, ROC)

  • RONG-TZONG WU

    (Synchrotron Radiation Research Center, Hsinchu, Taiwan, ROC)

  • CHIU-PING CHENG

    (Department of Physics, National Tsing-Hua University, Hsinchu, Taiwan, ROC)

Abstract

We present the first valence-band photoemission study ofBaandCson an atomically clean W(110) surface. The cleanness of the tungsten substrate can be justified from both high surface4fcore emission and sharp surface states in the valence-band spectra. UponBa (Cs)adsorption, the work function is lowered to 2.02 (1.76) eV, corresponding to one third of a monolayer. Further, the two symmetric high-lying surface states move little in energy but quench rapidly in intensity and diminish at the work-function minimum. On the other hand, the low-lying surface state at 1.41 eV shifts about 215 meV toward higher binding energy and reduces its emission at thicker coverage. The bonding of theBadorbital with the Wd-like surface states is not found, in contrast to the theoretical calculation and angle-resolved inverse photoemission study ofBaonW(100). From the coverage-dependent interfacial electronic structure and the parallel behaviors manifest in bothBaonWandCsonW, the polarized-covalent model for the alkali-metal–substrate interactions is firmly reinforced.

Suggested Citation

  • Tun-Wen Pi & Le-Hong Hong & Rong-Tzong Wu & Chiu-Ping Cheng, 1997. "VALENCE-BAND PHOTOEMISSION STUDY OF(Ba,Cs)onW(110)," Surface Review and Letters (SRL), World Scientific Publishing Co. Pte. Ltd., vol. 4(06), pages 1197-1201.
  • Handle: RePEc:wsi:srlxxx:v:04:y:1997:i:06:n:s0218625x9700153x
    DOI: 10.1142/S0218625X9700153X
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    Keywords

    ; 79.60 Gs; 68.55.Gi;
    All these keywords.

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