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Stability Of Two–Dimensional Surface Nitrides On Transition Metal Alloy Surfaces

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  • ELMARIE C. VILJOEN

    (Max-Planck-Institut für Eisenforschung, Postfach 140 444, D-40074 Düsseldorf, Germany)

  • CHRISTIAN UEBING

    (Max-Planck-Institut für Eisenforschung, Postfach 140 444, D-40074 Düsseldorf, Germany)

Abstract

The thermal stability of the two-dimensional surface nitrides CrN, MoN and WN has been studied on transition metal alloy surfaces. The surface nitrides are obtained by means of cosegregation of the constituents on Fe–15%Cr–N(100), Fe–3.5%Mo–N(100) and Fe–9%W–N(100) single crystals. The stability of the surface nitrides decreases in the sequence Cr>Mo>W, similar to the well-known three-dimensional bulk nitrides. All compounds exhibit1×1LEED structures, indicating epitaxial stabilization on the corresponding substrate surface. In a narrow temperature rangeT≈550°C the Fe–9%W–N(100) surface showsc(2×2)ordering of the segregated nitrogen atoms.

Suggested Citation

  • Elmarie C. Viljoen & Christian Uebing, 1997. "Stability Of Two–Dimensional Surface Nitrides On Transition Metal Alloy Surfaces," Surface Review and Letters (SRL), World Scientific Publishing Co. Pte. Ltd., vol. 4(04), pages 601-606.
  • Handle: RePEc:wsi:srlxxx:v:04:y:1997:i:04:n:s0218625x97000584
    DOI: 10.1142/S0218625X97000584
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    ; 68; 68.55.-a; 68.55.Nq; 68.65.+g;
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