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Collisional Processes Involving Size-Selected Sodium-Cluster Ions

Author

Listed:
  • H. TANAKA

    (Department of Chemistry, School of Science, University of Tokyo, Bunkyo-ku, Tokyo 113, Japan)

  • T. MIZUNO

    (Department of Chemistry, School of Science, University of Tokyo, Bunkyo-ku, Tokyo 113, Japan)

  • J. HIROKAWA

    (Department of Chemistry, School of Science, University of Tokyo, Bunkyo-ku, Tokyo 113, Japan)

  • S. NONOSE

    (Department of Chemistry, School of Science, University of Tokyo, Bunkyo-ku, Tokyo 113, Japan)

  • T. KONDOW

    (Department of Chemistry, School of Science, University of Tokyo, Bunkyo-ku, Tokyo 113, Japan)

Abstract

Collision-induced reactions of${\rm{Na}}_n^+$(n=2–9)with Ne and Kr were investigated by means of a Tandem mass spectrometer equipped with octapole ion guide. The dominant processes were evaporation of a Na atom from${\rm{Na}}_n^+$with even sizes orNa2molecules from those with odd sizes. The absolute cross section for the reaction was measured as functions of the parent-cluster size and the collision energy. The branching fractions of the daughter-ion production were also determined. These results are interpreted in a scheme of a pair interaction in jellium background.

Suggested Citation

  • H. Tanaka & T. Mizuno & J. Hirokawa & S. Nonose & T. Kondow, 1996. "Collisional Processes Involving Size-Selected Sodium-Cluster Ions," Surface Review and Letters (SRL), World Scientific Publishing Co. Pte. Ltd., vol. 3(01), pages 679-682.
    • Handle: RePEc:wsi:srlxxx:v:03:y:1996:i:01:n:s0218625x96001224
    DOI: 10.1142/S0218625X96001224
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