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DRAMATIC EFFECT ON LITHIUM-CLUSTER EVAPORATION: THE EXAMPLE OF${\rm Li}_{11}^+$

Author

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  • R. ANTOINE

    (Laboratoire de Spectromérie Ionique et Moléculaire (URA CNRS n° 171), Université Lyon 1, Bât. 205, 43 Bd du 11 Novembre, 1918 - 69622 Villeurbanne Cedex, France)

  • D. RAYANE

    (Laboratoire de Spectromérie Ionique et Moléculaire (URA CNRS n° 171), Université Lyon 1, Bât. 205, 43 Bd du 11 Novembre, 1918 - 69622 Villeurbanne Cedex, France)

  • PH. DUGOURD

    (Laboratoire de Spectromérie Ionique et Moléculaire (URA CNRS n° 171), Université Lyon 1, Bât. 205, 43 Bd du 11 Novembre, 1918 - 69622 Villeurbanne Cedex, France)

  • B. VEZIN

    (Laboratoire de Spectromérie Ionique et Moléculaire (URA CNRS n° 171), Université Lyon 1, Bât. 205, 43 Bd du 11 Novembre, 1918 - 69622 Villeurbanne Cedex, France)

  • B. TRIBOLLET

    (Laboratoire de Spectromérie Ionique et Moléculaire (URA CNRS n° 171), Université Lyon 1, Bât. 205, 43 Bd du 11 Novembre, 1918 - 69622 Villeurbanne Cedex, France)

  • M. BROYER

    (Laboratoire de Spectromérie Ionique et Moléculaire (URA CNRS n° 171), Université Lyon 1, Bât. 205, 43 Bd du 11 Novembre, 1918 - 69622 Villeurbanne Cedex, France)

Abstract

We have studied the unimolecular evaporation of ionized lithium clusters for different conditions of ionization. In this article we present the total evaporative rates and the monomer–dimer branching ratios for${\rm Li}_{11}^+$. We observe nonstatistical effects, associated with the dissociation along a less energetically favorable channel. Even after a few microseconds, the internal energy is probably not statistically distributed in all the vibrational modes.

Suggested Citation

  • R. Antoine & D. Rayane & Ph. Dugourd & B. Vezin & B. Tribollet & M. Broyer, 1996. "DRAMATIC EFFECT ON LITHIUM-CLUSTER EVAPORATION: THE EXAMPLE OF${\rm Li}_{11}^+$," Surface Review and Letters (SRL), World Scientific Publishing Co. Pte. Ltd., vol. 3(01), pages 545-549.
  • Handle: RePEc:wsi:srlxxx:v:03:y:1996:i:01:n:s0218625x96000991
    DOI: 10.1142/S0218625X96000991
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