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Xps Studies For An Iron-Zirconium Interface In An Oxidizing Environment

Author

Listed:
  • Y.S. LI

    (Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, British Columbia, Canada V6T 1Z1, Canada)

  • W. LIU

    (Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, British Columbia, Canada V6T 1Z1, Canada)

  • P.C. WONG

    (Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, British Columbia, Canada V6T 1Z1, Canada)

  • K.A.R. MITCHELL

    (Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, British Columbia, Canada V6T 1Z1, Canada)

Abstract

A bimetallic film of iron and zirconium (thicknesses about 17 and 52 Å respectively) was deposited on a gold substrate and studied by XPS after exposing toO2(approximately103L) at room temperature, and then heating at progressively higher temperatures up to 400°C. An iron-oxide/iron/zirconiumoxide sandwich structure is present after the room-temperature exposure toO2, and this work shows the ready transfer ofOfrom the iron side to the zirconium side of theFe/Zrinterface.Femigration also occurs at 220°C and above, while by 300°C this diffusion appears to cause a substantial restructuring of theZrO2layer.

Suggested Citation

  • Y.S. Li & W. Liu & P.C. Wong & K.A.R. Mitchell, 1995. "Xps Studies For An Iron-Zirconium Interface In An Oxidizing Environment," Surface Review and Letters (SRL), World Scientific Publishing Co. Pte. Ltd., vol. 2(06), pages 759-763.
    • Handle: RePEc:wsi:srlxxx:v:02:y:1995:i:06:n:s0218625x95000686
    DOI: 10.1142/S0218625X95000686
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