IDEAS home Printed from https://ideas.repec.org/a/wsi/acsxxx/v06y2003i01ns021952590300075x.html
   My bibliography  Save this article

Application Of Chemical Chaos To Analytical Chemistry

Author

Listed:
  • PETER E. STRIZHAK

    (L. V. Pysarzhevsky Institute of Physical Chemistry, National Academy of Sciences of Ukraine, pr. Nauki 31, Kiev, 03039, Ukraine)

Abstract

A simple theoretical consideration of the possibility of using deterministic chaos for a quantitative determination of trace amounts of chemical compounds is analyzed in terms of return maps. This allows the development of a general approach to find a calibration plot for a chemical compound determination, i.e. to find a one-to-one correspondence between a measured value and the concentration of a substance to be determined. As experimental verification of these theoretical results, we present a study of the effect of copper (II) ions on the transient chaotic regime in the BZ reaction catalyzed by ferroin in batch as well as of the effect of vanadium (IV) on the deterministic chaotic regime in the BZ reaction catalyzed by ferroin in a CSTR. These studies show that it is possible to quantify the response of transient chaotic regimes to chemical compounds, i.e. to construct a calibration plot for chemical compound determination using their effect on the chaotic dynamics in the BZ reaction. Moreover, these studies shown that vanadium (IV) affects the chaotic regimes at concentration levels of the order of10-12g/mL, which gives the best detection limit for the kinetic methods of trace analysis.

Suggested Citation

  • Peter E. Strizhak, 2003. "Application Of Chemical Chaos To Analytical Chemistry," Advances in Complex Systems (ACS), World Scientific Publishing Co. Pte. Ltd., vol. 6(01), pages 137-153.
    • Handle: RePEc:wsi:acsxxx:v:06:y:2003:i:01:n:s021952590300075x
    DOI: 10.1142/S021952590300075X
    as

    Download full text from publisher

    File URL: http://www.worldscientific.com/doi/abs/10.1142/S021952590300075X
    Download Restriction: Access to full text is restricted to subscribers
    File URL: https://libkey.io/10.1142/S021952590300075X?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:wsi:acsxxx:v:06:y:2003:i:01:n:s021952590300075x. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Tai Tone Lim (email available below). General contact details of provider: http://www.worldscinet.com/acs/acs.shtml .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.