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Equivalent Circuits Applied in Electrochemical Impedance Spectroscopy and Fractional Derivatives with and without Singular Kernel

Author

Listed:
  • J. F. Gómez-Aguilar
  • J. E. Escalante-Martínez
  • C. Calderón-Ramón
  • L. J. Morales-Mendoza
  • M. Benavidez-Cruz
  • M. Gonzalez-Lee

Abstract

We present an alternative representation of integer and fractional electrical elements in the Laplace domain for modeling electrochemical systems represented by equivalent electrical circuits. The fractional derivatives considered are of Caputo and Caputo‐Fabrizio type. This representation includes distributed elements of the Cole model type. In addition to maintaining consistency in adjusted electrical parameters, a detailed methodology is proposed to build the equivalent circuits. Illustrative examples are given and the Nyquist and Bode graphs are obtained from the numerical simulation of the corresponding transfer functions using arbitrary electrical parameters in order to illustrate the methodology. The advantage of our representation appears according to the comparison between our model and models presented in the paper, which are not physically acceptable due to the dimensional incompatibility. The Markovian nature of the models is recovered when the order of the fractional derivatives is equal to 1.

Suggested Citation

  • J. F. Gómez-Aguilar & J. E. Escalante-Martínez & C. Calderón-Ramón & L. J. Morales-Mendoza & M. Benavidez-Cruz & M. Gonzalez-Lee, 2016. "Equivalent Circuits Applied in Electrochemical Impedance Spectroscopy and Fractional Derivatives with and without Singular Kernel," Advances in Mathematical Physics, John Wiley & Sons, vol. 2016(1).
    • Handle: RePEc:wly:jnlamp:v:2016:y:2016:i:1:n:9720181
    DOI: 10.1155/2016/9720181
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    1. J.F. Gómez-Aguilar & H. Yépez-Martínez & R.F. Escobar-Jiménez & C.M. Astorga-Zaragoza & L.J. Morales-Mendoza & M. González-Lee, 2015. "Universal character of the fractional space-time electromagnetic waves in dielectric media," Journal of Electromagnetic Waves and Applications, Taylor & Francis Journals, vol. 29(6), pages 727-740, April.
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