Structural-textural nature and sorption properties of limestones from the mesozoic-neogene contact zone in the Bełchatów deposit

Limestones of the Jurassic age are one of the most important minerals accompanying the Bełchatówlignite deposits. They are part of the Bełchatów and Szczerców rock subsoil complex and form natural hillsides of exploitation fields, which are gradually being exposed due to the progressive exploitation of coal. So far in Bełchatów Lignite Mine nearly 2 million tonnes of limestones have been extracted, which were used in the form of highway aggregate. For the extraction (mineral recovery) approx. 2 million tonnes remained in the Bełchatów field and from 20 to nearly 70 million tonnes in the Szczerców field. The limestones occurring in the deposit Bełchatów are differential qualitatively. Those situated in direct contact with Neogene deposits are characterized by strong karstification (karst formation), and even occur in the form of detrital minerals. Furthermore, they are covered by processes of secondary mineralization. These processes caused significant diversity of phase and chemical composition, and thereby have contributed to reducing the CaCO3 content. Despite this, limestones from the Mesozoic-Neogene contact zone possess excellent sorption properties in respect of SO2 in conditions of fluidised furnaces. These properties are determined firstly by their structural-textural nature, and above all with the presence of calcite sparite crystals in microcrystalline groundmass, of micropores, tectonic discontinuities, fracturings and compaction slits. With their presence, both decarbonatization and sorption processes proceed effectively. The CO2 particles are quickly removed from the structures of calcite crystals, and SO2 is able to penetrate into the interior of the sorbent grains where are absorbed on the inner surface of pores arising as a result of the decarbonatization process. These characteristic structural and textural properties of the surveyed limestones have been shaped at the diagenesis and epigenesis stage. This contributed to all chemical and mechanical compaction and cementation processes, as well as the dissolution and recrystallization processes. Despite the low CaCO3 content limestones from the Mesozoic-Neogene contact zone can be successfully used in the form of sorbents to reduce SO2 emissions in conditions of fluidised furnaces.