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Electron spin resonance of Eu 2 + in the Eu doped clathrate Ba 6 Ge 25

Author

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  • J. Sichelschmidt
  • W. Carrillo-Cabrera
  • V. A. Ivanshin
  • Yu. Grin
  • F. Steglich

Abstract

We report electron spin resonance (ESR) investigations of the clathrate compound Ba 6-x Eu x Ge 25 (x=0.03–0.4) which exhibits a temperature induced, two-step reconstructive structure transformation at temperatures between 185 K and 223 K. The linewidth of the Eu 2+ ESR proves to be sensitive to the transformation. Another anomaly in the temperature dependence of the linewidth is found near T=60 K which points towards another possible structural transition. Both anomalies seen in the ESR linewidth are not sensitive to the Eu content in contrast to the strong Eu-concentration dependence of transport properties. Copyright EDP Sciences/Società Italiana di Fisica/Springer-Verlag 2005

Suggested Citation

  • J. Sichelschmidt & W. Carrillo-Cabrera & V. A. Ivanshin & Yu. Grin & F. Steglich, 2005. "Electron spin resonance of Eu 2 + in the Eu doped clathrate Ba 6 Ge 25," The European Physical Journal B: Condensed Matter and Complex Systems, Springer;EDP Sciences, vol. 46(2), pages 201-205, July.
    • Handle: RePEc:spr:eurphb:v:46:y:2005:i:2:p:201-205
    DOI: 10.1140/epjb/e2005-00246-8
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