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Identification of an iridium-containing compound with a formal oxidation state of IX

Author

Listed:
  • Guanjun Wang

    (Collaborative Innovation Center of Chemistry for Energy Materials, Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Fudan University)

  • Mingfei Zhou

    (Collaborative Innovation Center of Chemistry for Energy Materials, Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Fudan University)

  • James T. Goettel

    (McMaster University, 1280 Main Street West, Hamilton, Ontario L8S 4M1, Canada)

  • Gary J. Schrobilgen

    (McMaster University, 1280 Main Street West, Hamilton, Ontario L8S 4M1, Canada)

  • Jing Su

    (Tsinghua University, Beijing 100084, China)

  • Jun Li

    (Tsinghua University, Beijing 100084, China)

  • Tobias Schlöder

    (Institut für Anorganische und Analytische Chemie, Albert-Ludwigs Universität Freiburg, Albertstrasse 21, D-79104 Freiburg im Breisgau, Germany)

  • Sebastian Riedel

    (Institut für Anorganische und Analytische Chemie, Albert-Ludwigs Universität Freiburg, Albertstrasse 21, D-79104 Freiburg im Breisgau, Germany
    Institut für Chemie und Biochemie – Anorganische Chemie, Freie Universität Berlin, Fabeckstrasse 34-36, D-14195 Berlin, Germany)

Abstract

The tetrahedral iridium tetroxide cation [IrO4]+, which has an iridium 5d0 valence electron configuration and a formal oxidation state of IX, is generated in the gas phase, identified by infrared photodissociation spectroscopy, and predicted, by quantum chemical calculations, to be the most stable of all possible [IrO4]+ isomers.

Suggested Citation

  • Guanjun Wang & Mingfei Zhou & James T. Goettel & Gary J. Schrobilgen & Jing Su & Jun Li & Tobias Schlöder & Sebastian Riedel, 2014. "Identification of an iridium-containing compound with a formal oxidation state of IX," Nature, Nature, vol. 514(7523), pages 475-477, October.
    • Handle: RePEc:nat:nature:v:514:y:2014:i:7523:d:10.1038_nature13795
    DOI: 10.1038/nature13795
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