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Catalytic enantioselective reactions driven by photoinduced electron transfer

Author

Listed:
  • Andreas Bauer

    (Technische Universität München)

  • Felix Westkämper

    (Technische Universität München)

  • Stefan Grimme

    (Universität Münster, Organisch-Chemisches Institut)

  • Thorsten Bach

    (Technische Universität München)

Abstract

Control your excitement Photoinduced electron transfer uses light absorption to generate molecules in excited electronic states susceptible to accepting or donating electrons. This can be a good way of synthesizing organic chemicals, but the involvement of excited states makes it hard to control the nature of the reaction products. By using an appropriately chosen organocatalyst, Bauer et al. show how such a reaction can be made to proceed in an enantioselective manner, yielding the desired product at high chiral purity.

Suggested Citation

  • Andreas Bauer & Felix Westkämper & Stefan Grimme & Thorsten Bach, 2005. "Catalytic enantioselective reactions driven by photoinduced electron transfer," Nature, Nature, vol. 436(7054), pages 1139-1140, August.
    • Handle: RePEc:nat:nature:v:436:y:2005:i:7054:d:10.1038_nature03955
    DOI: 10.1038/nature03955
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