Author
Listed:
- Aimée Rose
(Department of Chemistry)
- Zhengguo Zhu
(Department of Chemistry)
- Conor F. Madigan
(Massachusetts Institute of Technology)
- Timothy M. Swager
(Department of Chemistry)
- Vladimir Bulović
(Massachusetts Institute of Technology)
Abstract
Societal needs for greater security require dramatic improvements in the sensitivity of chemical and biological sensors. To meet this challenge, increasing emphasis in analytical science has been directed towards materials and devices having highly nonlinear characteristics; semiconducting organic polymers (SOPs), with their facile excited state (exciton) transport, are prime examples of amplifying materials1,2,3. SOPs have also been recognized as promising lasing materials4, although the susceptibility of these materials to optical damage has thus far limited applications. Here we report that attenuated lasing in optically pumped SOP thin films displays a sensitivity to vapours of explosives more than 30 times higher than is observed from spontaneous emission. Critical to this achievement was the development of a transducing polymer with high thin-film quantum yield, a high optical damage threshold in ambient atmosphere and a record low lasing threshold. Trace vapours of the explosives 2,4,6-trinitrotoluene (TNT) and 2,4-dinitrotoluene (DNT) introduce non-radiative deactivation pathways5 that compete with stimulated emission. We demonstrate that the induced cessation of the lasing action, and associated sensitivity enhancement, is most pronounced when films are pumped at intensities near their lasing threshold. The combined gains from amplifying materials and lasing promise to deliver sensors that can detect explosives with unparalleled sensitivity.
Suggested Citation
Aimée Rose & Zhengguo Zhu & Conor F. Madigan & Timothy M. Swager & Vladimir Bulović, 2005.
"Sensitivity gains in chemosensing by lasing action in organic polymers,"
Nature, Nature, vol. 434(7035), pages 876-879, April.
Handle:
RePEc:nat:nature:v:434:y:2005:i:7035:d:10.1038_nature03438
DOI: 10.1038/nature03438
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