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Overcoming humidity-induced swelling of graphene oxide-based hydrogen membranes using charge-compensating nanodiamonds

Author

Listed:
  • Guoji Huang

    (Kyoto University
    Kyoto University)

  • Behnam Ghalei

    (Kyoto University
    Kyoto University)

  • Ali Pournaghshband Isfahani

    (Kyoto University
    Kyoto University)

  • H. Enis Karahan

    (Kyoto University
    Kyoto University)

  • Daiki Terada

    (Kyoto University)

  • Detao Qin

    (Kyoto University
    Kyoto University)

  • Conger Li

    (ShanghaiTech University)

  • Masahiko Tsujimoto

    (Kyoto University)

  • Daisuke Yamaguchi

    (Kyoto University
    Kyoto University)

  • Kunihisa Sugimoto

    (Kyoto University
    Division of Diffraction and Scattering, Japan Synchrotron Radiation Research Institute (JASRI), Sayo-Cho, Sayo-gun)

  • Ryuji Igarashi

    (National Institutes for Quantum Science and Technology)

  • Bor Kae Chang

    (National Central University
    Chung Yuan Christian University)

  • Tao Li

    (ShanghaiTech University)

  • Masahiro Shirakawa

    (Kyoto University)

  • Easan Sivaniah

    (Kyoto University
    Kyoto University)

Abstract

Graphene oxide (GO) can form ultrapermeable and ultraselective membranes that are promising for various gas separation applications, including hydrogen purification. However, GO films lose their attractive separation properties in humid conditions. Here we show that incorporating positively charged nanodiamonds (ND+s) into GO nanolaminates leads to humidity-resistant, yet high-performing, membranes. While native GO membranes fail at a single run, the GO/ND+ composite retains up to roughly 90% of GO’s H2 selectivity against CO2 after several cycles under an aggressive humidity test. The addition of negatively charged ND to GO brought no such stabilization, suggesting that charge compensation acts as the main mechanism conferring humidity resistance, where ND+s neutralize the negative charge GO sheets. We observed a similar but inferior stabilization effect when positively charged polyhedral oligomeric silsesquioxane replaces ND+. The demonstrated material platform offers a solution for separating H2 gas from its usually humid mixtures generated from fossil fuel sources or water splitting.

Suggested Citation

  • Guoji Huang & Behnam Ghalei & Ali Pournaghshband Isfahani & H. Enis Karahan & Daiki Terada & Detao Qin & Conger Li & Masahiko Tsujimoto & Daisuke Yamaguchi & Kunihisa Sugimoto & Ryuji Igarashi & Bor K, 2021. "Overcoming humidity-induced swelling of graphene oxide-based hydrogen membranes using charge-compensating nanodiamonds," Nature Energy, Nature, vol. 6(12), pages 1176-1187, December.
    • Handle: RePEc:nat:natene:v:6:y:2021:i:12:d:10.1038_s41560-021-00946-y
    DOI: 10.1038/s41560-021-00946-y
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    Cited by:

    1. Paolo Tronville & Vincenzo Gentile & Jesus Marval, 2023. "Guidelines for measuring and reporting particle removal efficiency in fibrous media," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    2. Kecheng Guan & Yanan Guo & Zhan Li & Yuandong Jia & Qin Shen & Keizo Nakagawa & Tomohisa Yoshioka & Gongping Liu & Wanqin Jin & Hideto Matsuyama, 2023. "Deformation constraints of graphene oxide nanochannels under reverse osmosis," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    3. Yuan Kang & Ting Hu & Yuqi Wang & Kaiqiang He & Zhuyuan Wang & Yvonne Hora & Wang Zhao & Rongming Xu & Yu Chen & Zongli Xie & Huanting Wang & Qinfen Gu & Xiwang Zhang, 2023. "Nanoconfinement enabled non-covalently decorated MXene membranes for ion-sieving," Nature Communications, Nature, vol. 14(1), pages 1-9, December.

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