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Formation of metallic cation-oxygen network for anomalous thermal expansion coefficients in binary phosphate glass

Author

Listed:
  • Yohei Onodera

    (Research Reactor Institute
    Light/Quantum Beam Field, Research Center for Advanced Measurement and Characterization, National Institute for Materials Science (NIMS))

  • Shinji Kohara

    (Light/Quantum Beam Field, Research Center for Advanced Measurement and Characterization, National Institute for Materials Science (NIMS)
    Information Integrated Materials Design Field, Center for Materials Research by Information Integration
    PRESTO, Japan Science and Technology Agency
    Japan Synchrotron Radiation Research Institute/SPring-8)

  • Hirokazu Masai

    (Institute for Chemical Research, Kyoto University
    Present address: Department of Materials and Chemistry, National Institute of Advanced Industrial Science and Technology (AIST), 1-8-31 Midorigaoka, Ikeda, Osaka 563-8577, Japan)

  • Akitoshi Koreeda

    (Ritsumeikan University)

  • Shun Okamura

    (Institute for Chemical Research, Kyoto University)

  • Takahiro Ohkubo

    (Graduate School & Faculty of Engineering, Chiba University)

Abstract

Understanding glass structure is still challenging due to the result of disorder, although novel materials design on the basis of atomistic structure has been strongly demanded. Here we report on the atomic structures of the zinc phosphate glass determined by reverse Monte Carlo modelling based on diffraction and spectroscopic data. The zinc-rich glass exhibits the network formed by ZnOx (averaged x

Suggested Citation

  • Yohei Onodera & Shinji Kohara & Hirokazu Masai & Akitoshi Koreeda & Shun Okamura & Takahiro Ohkubo, 2017. "Formation of metallic cation-oxygen network for anomalous thermal expansion coefficients in binary phosphate glass," Nature Communications, Nature, vol. 8(1), pages 1-8, August.
    • Handle: RePEc:nat:natcom:v:8:y:2017:i:1:d:10.1038_ncomms15449
    DOI: 10.1038/ncomms15449
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