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Bio-based polycarbonate as synthetic toolbox

Author

Listed:
  • O. Hauenstein

    (Macromolecular Chemistry II and Center for Colloids and Interfaces, University of Bayreuth)

  • S. Agarwal

    (Macromolecular Chemistry II and Center for Colloids and Interfaces, University of Bayreuth)

  • A. Greiner

    (Macromolecular Chemistry II and Center for Colloids and Interfaces, University of Bayreuth)

Abstract

Completely bio-based poly(limonene carbonate) is a thermoplastic polymer, which can be synthesized by copolymerization of limonene oxide (derived from limonene, which is found in orange peel) and CO2. Poly(limonene carbonate) has one double bond per repeating unit that can be exploited for further chemical modifications. These chemical modifications allow the tuning of the properties of the aliphatic polycarbonate in nearly any direction. Here we show synthetic routes to demonstrate that poly(limonene carbonate) is the perfect green platform polymer, from which many functional materials can be derived. The relevant examples presented in this study are the transformation from an engineering thermoplastic into a rubber, addition of permanent antibacterial activity, hydrophilization and even pH-dependent water solubility of the polycarbonate. Finally, we show a synthetic route to yield the completely saturated counterpart that exhibits improved heat processability due to lower reactivity.

Suggested Citation

  • O. Hauenstein & S. Agarwal & A. Greiner, 2016. "Bio-based polycarbonate as synthetic toolbox," Nature Communications, Nature, vol. 7(1), pages 1-7, September.
    • Handle: RePEc:nat:natcom:v:7:y:2016:i:1:d:10.1038_ncomms11862
    DOI: 10.1038/ncomms11862
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    Cited by:

    1. Zvanaka S. Mazhandu & Edison Muzenda & Tirivaviri A. Mamvura & Mohamed Belaid & Trust Nhubu, 2020. "Integrated and Consolidated Review of Plastic Waste Management and Bio-Based Biodegradable Plastics: Challenges and Opportunities," Sustainability, MDPI, vol. 12(20), pages 1-57, October.

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