IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v5y2014i1d10.1038_ncomms6844.html
   My bibliography  Save this article

Bottom-up formation of endohedral mono-metallofullerenes is directed by charge transfer

Author

Listed:
  • Paul W. Dunk

    (Florida State University, 95 Chieftain Way, Tallahassee, Florida 32306, USA
    Ion Cyclotron Resonance Program, National High Magnetic Field Laboratory, Florida State University)

  • Marc Mulet-Gas

    (Departament de Química Física i Inorgànica, Universitat Rovira i Virgili)

  • Yusuke Nakanishi

    (Nagoya University)

  • Nathan K. Kaiser

    (Ion Cyclotron Resonance Program, National High Magnetic Field Laboratory, Florida State University)

  • Antonio Rodríguez-Fortea

    (Departament de Química Física i Inorgànica, Universitat Rovira i Virgili)

  • Hisanori Shinohara

    (Nagoya University)

  • Josep M. Poblet

    (Departament de Química Física i Inorgànica, Universitat Rovira i Virgili)

  • Alan G. Marshall

    (Florida State University, 95 Chieftain Way, Tallahassee, Florida 32306, USA
    Ion Cyclotron Resonance Program, National High Magnetic Field Laboratory, Florida State University)

  • Harold W. Kroto

    (Florida State University, 95 Chieftain Way, Tallahassee, Florida 32306, USA)

Abstract

An understanding of chemical formation mechanisms is essential to achieve effective yields and targeted products. One of the most challenging endeavors is synthesis of molecular nanocarbon. Endohedral metallofullerenes are of particular interest because of their unique properties that offer promise in a variety of applications. Nevertheless, the mechanism of formation from metal-doped graphite has largely eluded experimental study, because harsh synthetic methods are required to obtain them. Here we report bottom-up formation of mono-metallofullerenes under core synthesis conditions. Charge transfer is a principal factor that guides formation, discovered by study of metallofullerene formation with virtually all available elements of the periodic table. These results could enable production strategies that overcome long-standing problems that hinder current and future applications of metallofullerenes.

Suggested Citation

  • Paul W. Dunk & Marc Mulet-Gas & Yusuke Nakanishi & Nathan K. Kaiser & Antonio Rodríguez-Fortea & Hisanori Shinohara & Josep M. Poblet & Alan G. Marshall & Harold W. Kroto, 2014. "Bottom-up formation of endohedral mono-metallofullerenes is directed by charge transfer," Nature Communications, Nature, vol. 5(1), pages 1-8, December.
  • Handle: RePEc:nat:natcom:v:5:y:2014:i:1:d:10.1038_ncomms6844
    DOI: 10.1038/ncomms6844
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/ncomms6844
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/ncomms6844?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:5:y:2014:i:1:d:10.1038_ncomms6844. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.