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Trinucleotide duplex formation inside a confined nanospace under supercooled conditions

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  • Hiroyuki Arafune

    (Graduate School of Science, Tohoku University
    Present address: Tsuruoka National College of Technology, Tsuruoka, Yamagata 997-8511, Japan)

  • Akira Yamaguchi

    (College of Science, Ibaraki University)

  • Manato Namekawa

    (Graduate School of Science, Tohoku University)

  • Yusuke Sato

    (Graduate School of Science, Tohoku University)

  • Tetsuji Itoh

    (Research Center for Compact Chemical System, National Institute of Advanced Industrial Science and Technology (AIST))

  • Ryoko Yoshida

    (College of Science, Ibaraki University)

  • Norio Teramae

    (Graduate School of Science, Tohoku University)

Abstract

Self-assembly of nucleotides of fewer than three base pairs is often found in protein–nucleotide conjugations, despite their energetic instability, and is regarded as the potential starting point for the creation of artificial hydrogen-bonded supramolecular complexes. Here we report duplex formation of 3-mer DNA fragments confined within silica mesopores modified with a positively charged trimethyl aminopropyl monolayer, and their further stabilization under supercooled conditions (T

Suggested Citation

  • Hiroyuki Arafune & Akira Yamaguchi & Manato Namekawa & Yusuke Sato & Tetsuji Itoh & Ryoko Yoshida & Norio Teramae, 2014. "Trinucleotide duplex formation inside a confined nanospace under supercooled conditions," Nature Communications, Nature, vol. 5(1), pages 1-7, December.
    • Handle: RePEc:nat:natcom:v:5:y:2014:i:1:d:10.1038_ncomms6151
    DOI: 10.1038/ncomms6151
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